[Ti(cyclopentadienyl)(η5-C5H4CH2CH2CH2NH(CH3)2]Cl | 554414-95-8

• 英文名称: [Ti(cyclopentadienyl)(η5-C5H4CH2CH2CH2NH(CH3)2]Cl
• CAS: 554414-95-8
• 化学式: C₁₅H₂₂Cl₂NTi*Cl
• 分子量: 370.585
• InChiKey: PEWVZFZAVPMIPT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 [Ti(cyclopentadienyl)(η5-C5H4CH2CH2CH2NH(CH3)2]Cl 以 甲醇 为溶剂， 生成 [Ti(cyclopentadienyl)(η5-C5H4CH2CH2CH2NH(CH3)2]Cl*methanol
  参考文献：
  名称：

  Synthesis of titanium(IV) (cyclopentadienylalkyl)aminate complexes

  摘要：

  We describe the synthesis of hydrochlorides of [TiCp{(C5H4(CH2)(n)NMe2}Cl-2] (n = 2 or 3) via [TiCpCl3] and the lithiated (cyclopentadienylalky)lamine. The -NHMe2 groups in these complexes are not coordinated to the titanium, and probably not in the parent amines either, the metal stereochemistry being the same in each group of compounds. The structure of [TiCp(eta(5)- C5H4CH2CH2CH2NHMe2)Cl-2]Cl is described in detail. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02223-4
• 作为产物：
  描述：

  盐酸 、 Ti(cyclopentadienyl)(η5-C5H4CH2CH2CH2N(CH3)2)Cl2 以 甲醇 为溶剂， 以81%的产率得到[Ti(cyclopentadienyl)(η5-C5H4CH2CH2CH2NH(CH3)2]Cl
  参考文献：
  名称：

  Synthesis of titanium(IV) (cyclopentadienylalkyl)aminate complexes

  摘要：

  We describe the synthesis of hydrochlorides of [TiCp{(C5H4(CH2)(n)NMe2}Cl-2] (n = 2 or 3) via [TiCpCl3] and the lithiated (cyclopentadienylalky)lamine. The -NHMe2 groups in these complexes are not coordinated to the titanium, and probably not in the parent amines either, the metal stereochemistry being the same in each group of compounds. The structure of [TiCp(eta(5)- C5H4CH2CH2CH2NHMe2)Cl-2]Cl is described in detail. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02223-4