1,1'-((((oxybis(methylene))bis(2-phenyl-1,3-dioxane-5,5-diyl))bis(methylene))bis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) | 929038-91-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: 1,1'-((((oxybis(methylene))bis(2-phenyl-1,3-dioxane-5,5-diyl))bis(methylene))bis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
• CAS: 929038-91-5
• 化学式: C₄₀H₆₈N₄O₇P₂
• 分子量: 778.95
• InChiKey: YIYHDQLZXNXPSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.32
• 重原子数：
  53.0
• 可旋转键数：
  24.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  77.57
• 氢给体数：
  0.0
• 氢受体数：
  11.0

反应信息

• 作为反应物：
  描述：

  1,1'-((((oxybis(methylene))bis(2-phenyl-1,3-dioxane-5,5-diyl))bis(methylene))bis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) 在 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 以0.42 g的产率得到1,7-tetraethyldiamidothionophosphate-2',2'':6',6''-di-O-benzylidene-2',2'',6',6''-tetra-(hydroxymethyl)-4-oxa-heptanediol
  参考文献：
  名称：

  Dipentaerethrite in the synthesis of model amidophosphate phospholipids

  摘要：

  A productive method for the synthesis of original phospholipid architectures is developed based on the available reagent dipentaerythritol. Introduction of the phosphoric function to the system is achieved by using phosphoric hexaethyltriamide.

  DOI：

  10.1134/s1070363206070073
• 作为产物：
  描述：

  双季戊四醇 在 盐酸 作用下， 以 1,4-二氧六环 、 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 25.0 ℃ 、13.33 kPa 条件下， 反应 15.0h， 生成 1,1'-((((oxybis(methylene))bis(2-phenyl-1,3-dioxane-5,5-diyl))bis(methylene))bis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
  参考文献：
  名称：

  Dipentaerethrite in the synthesis of model amidophosphate phospholipids

  摘要：

  A productive method for the synthesis of original phospholipid architectures is developed based on the available reagent dipentaerythritol. Introduction of the phosphoric function to the system is achieved by using phosphoric hexaethyltriamide.

  DOI：

  10.1134/s1070363206070073

文献信息

• New phosphorus-containing macroheterocyclic cavitands
  作者：D. A. Predvoditelev、M. A. Malenkovskaya、E. E. Nifant’ev

  DOI：10.1134/s1070363206080056

  日期：2006.8

  Previously unknown phosphorus-containing macroheterocycles were prepared from an accessible symmetrical dipentaerythritol derivative and trivalent phosphorus compounds. The difference in the properties of the phosphocycles containing one and two phosphoric functions was revealed.
• Dietylpentaerythritol diacetals in the synthesis of phosphorus containing macroheterocycles
  作者：E. E. Nifant’ev、D. A. Predvoditelev、M. A. Malenkovskaya

  DOI：10.1134/s1070363207030164

  日期：2007.3

  Synthesis of phosphorus-containing macroheterocycles based on the symmetrical dipentaerytritol diacetals and trivalent phosphorus reagent is studied. Effective peracetalization of dimethoxymethane with dipentaerytritol is performed.