sodium;2-[[(1S)-1-carboxy-2-methylpropyl]iminomethyl]-4-chloro-6-nitrophenolate | 1401340-23-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: sodium;2-[[(1S)-1-carboxy-2-methylpropyl]iminomethyl]-4-chloro-6-nitrophenolate
• CAS: 1401340-23-5
• 化学式: C₁₂H₁₂ClN₂O₅*Na
• 分子量: 322.68
• InChiKey: SDOVFAZUCOZALM-PPHPATTJSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.15
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  119
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  L-缬氨酸 、 5-氯-3-硝基水杨醛 在 sodium 作用下， 以 甲醇 为溶剂， 反应 3.0h， 生成 sodium;2-[[(1S)-1-carboxy-2-methylpropyl]iminomethyl]-4-chloro-6-nitrophenolate
  参考文献：
  名称：

  Binuclear cobalt complex with Schiff base ligand: Synthesis, characterization and catalytic properties in partial oxidation of cyclohexane

  摘要：

  A new binuclear cobalt complex with Schiff base ligand and amino acid was synthesized and characterized using XRD, elemental analysis, IR spectroscopy, XPS and electrochemical measurements. The presence of cobalt in the oxidation state 3+ in this complex was proved. The catalytic activity of this complex was investigated in the reaction of partial cyclohexane oxidation with air, and high activity and selectivity for cyclohexanol and cyclohexanone formation were demonstrated. The possibility of complex reuse in cyclohexane oxidation was studied and it was shown that the activity slightly decreases in a second oxidation cycle along with changes in main product distribution due to partial transfer of Co3+ to Co2+. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.06.017