α-Chlorcyclohexanon-cis-oxim | 88589-64-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: α-Chlorcyclohexanon-cis-oxim
• 英文别名: (NZ)-N-(2-chlorocyclohexylidene)hydroxylamine
• CAS: 88589-64-4
• 化学式: C₆H₁₀ClNO
• 分子量: 147.605
• InChiKey: ODCQZCNSWWLGCQ-VURMDHGXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  α-Chlorcyclohexanon-cis-oxim 、 2-氯环己酮肟环己烷羧酸盐 、 三乙胺 生成 1-Nitroso-cyclohexen
  参考文献：
  名称：

  DENMARK, S. E.;DAPPEN, M. S., J. ORG. CHEM., 1984, 49, N 5, 798-806

  摘要：

  DOI：
• 作为产物：
  描述：

  2-氯环己酮 、 羟胺 生成 α-Chlorcyclohexanon-cis-oxim
  参考文献：
  名称：

  DENMARK, S. E.;DAPPEN, M. S., J. ORG. CHEM., 1984, 49, N 5, 798-806

  摘要：

  DOI：

文献信息

• Stabilising polymeric, organosilicon or silicone compositions
  申请人：——

  公开号：US20040097663A1

  公开（公告）日：2004-05-20

  The invention relates to polyorganosiloxane polymers to which antioxidant functional groups have been grafted. These polymers can be used for the stabilization of polymer compositions, in particular non-organosilicon organic polymer compositions and silicone compositions. More particularly, they are used to stabilize silicone compositions intended for the preparation of moulds, in particular of moulds for the moulding of polyester items.

  本发明涉及将抗氧化剂官能团嫁接到聚有机硅氧烷聚合物上。这些聚合物可以用于稳定聚合物组合物，特别是非有机硅有机聚合物组合物和硅氧烷组合物。更具体地，它们用于稳定硅氧烷组合物，用于制备模具，特别是用于制造聚酯制品的模具。
• Crosslinkable liquid silicone composition comprising a low viscosifying filler based on zirconium, use of same as fire-resistant coating
  申请人：——

  公开号：US20040059034A1

  公开（公告）日：2004-03-25

  The invention concerns crosslinkable liquid silicone compositions whereof the inorganic filler can be increased while observing limits of viscosity compatible with coating of woven or nonwoven supports on an industrial scale, and which impart to the supports thermal properties (reducing calorific power and fire-proofing), impermeability and good mechanical characteristics. To achieve this, a mineral compound is used based on zirconium (zirconia or zirconium silicate) as filler slightly thickening ChZr in a crosslinkable liquid silicone composition. The ChZr has a D50 ranging between 3 and 15 &mgr;m and is used in a proportion of 100 to 350 parts by weight for 100 parts by weight of the silicone composition without fillers. Said silicone compositions may be of the type crosslinkable by polyaddition or polycondensation. The invention is useful for silicone coating textile tarpaulins for indoor or outdoor structures.

  本发明涉及可交联的液态硅橡胶组合物，其中无机填料可以增加，同时观察到与工业规模上织物或非织造物支撑物的涂覆相容的粘度限制，并赋予支撑物热性能（降低热值和防火性）、不透水性和良好的机械特性。为了实现这一目的，使用基于锆的矿物化合物（氧化锆或二氧化锆硅酸盐）作为填料，略微增稠可交联液态硅橡胶组合物中的ChZr。ChZr的D50值在3至15μm之间，按重量比100份硅橡胶组合物不含填料使用100至350份。所述硅橡胶组合物可以是通过聚加或聚合反应交联的类型。本发明对于硅橡胶涂覆室内或室外结构的纺织品篷布非常有用。
• Process for the prepration of a suspension of silica in an optionally crosslinkable silicone matrix
  申请人：——

  公开号：US20040044113A1

  公开（公告）日：2004-03-04

  The invention relates to the preparation of a suspension of precipitated silica in a silicone oil, this suspension being usable for the production of silicones crosslinkable by polyaddition or polycondensation (RTV elastomers). The object of the invention is to seek a compromise between on the one hand the cost and on the other hand the rheology and mechanical properties of the final RTVs. The invention achieves this object by providing a process for the preparation of a suspension of precipitated silica, treated with hexamethyldisilazane (HMDZ), in a crosslinkable silicone oil. This HMDZ is introduced in at least two fractions. The 1st fraction on the one hand corresponds to a proportion less than or equal to 15% by dry weight, based on the total amount of HMDZ, and on the other hand is first brought into contact with the precipitated silica and the water. The invention further relates to the production of a silicone elastomer composition from this suspension and to the composition thus obtained.

  本发明涉及制备一种在硅油中沉淀二氧化硅的悬浮液，该悬浮液可用于制备通过聚加或聚缩交联的硅橡胶（RTV弹性体）。本发明的目的是在成本和最终RTV的流变性和机械性能之间寻求一种折衷方案。本发明通过提供一种处理了六甲基二硅氮烷（HMDZ）的沉淀二氧化硅悬浮液的制备过程来实现该目的。该HMDZ分两部分引入。一方面，第一部分对应于干重不大于总HMDZ量的15％，另一方面，首先与沉淀二氧化硅和水接触。本发明还涉及从该悬浮液制备硅橡胶组合物以及由此得到的组合物。
• Method for stabilising silicone elastomer moulds
  申请人：——

  公开号：US20030149170A1

  公开（公告）日：2003-08-07

  The invention concerns the use for increasing the life span of moulds made of silicone elastomer crosslinking by polyaddition or polycondensation reaction, of an additive capable of stabilising the silicone elastomer whereof the mould is constituted with respect to materials to be moulded, said additive corresponding the following formula (1) wherein R 1 and R 2 are linear or branched alkyl radicals or cycloaliphatic radicals having 1 to 40 carbon atoms. Preferably, said additive is methyl laurylthiopropionate. C 12 H 25 —S—CH 3 —CH 2 —CO—O—CH 3 . The invention also concerns the corresponding silicone compositions and the resulting moulds.

  本发明涉及使用一种添加剂来增加通过聚加成或聚缩成反应交联的硅弹性体制成的模具的寿命，该添加剂能够稳定硅弹性体，使其对于要制成的材料具有稳定性，该添加剂对应于以下式子（1），其中R1和R2是具有1到40个碳原子的线性或支链烷基基团或环状脂肪基团。优选地，该添加剂是硫代丙酸月桂酯。C12H25—S—CH3—CH2—CO—O— 。本发明还涉及相应的硅复合物和制成的模具。
• Method for preparing a silica suspension in an potentially crosslinkable silicone material
  申请人：Chaussade Marc

  公开号：US20060241222A1

  公开（公告）日：2006-10-26

  The invention concerns a method for preparing a precipitated silica suspension in a silicone oil, said suspension being useable for producing silicones crosslinkable by polyaddition, polycondensation or condensation by dehydrogenation (elastomers). The invention aims at solving the problem of finding a compromise between cost, rheology and mechanical properties of the final elastomers. Therefore, the invention provides a method for preparing a precipitated silica suspension treated with trimethylchlorosilane, in the presence of hexamethyldisiloxane, in a crosslinkable silicone oil. HCl can be used. Grafting of the hydrophobic units on the silica and incorporation of the polyorganosiloxane silicone material are carried out during one single processing sequence, without passing through the powder form for the silica. Sodium silicate promoting MQ resin can be incorporated in the reaction medium. The invention also concerns the preparation of a crosslinkable silicone elastomer composition from said suspension, and the resulting composition.

  本发明涉及一种在硅油中制备沉淀二氧化硅悬浮液的方法，该悬浮液可用于生产通过聚加、聚缩或脱氢缩合（弹性体）交联的硅烷。本发明旨在解决在最终弹性体的成本、流变学和机械性能之间找到平衡的问题。因此，本发明提供了一种在可交联的硅油中处理了三甲基氯硅烷的沉淀二氧化硅悬浮液的制备方法，在六甲基二硅氧烷的存在下进行。可以使用HCl。在一次处理序列中进行硅胶上的疏水基的接枝和聚有机硅氧烷硅材料的纳入，而无需通过硅胶的粉末形式。可以在反应介质中加入促进MQ树脂的硅酸钠。本发明还涉及从该悬浮液中制备可交联的硅烷弹性体组合物以及所得到的组合物。