| 1393088-97-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1393088-97-5
• 化学式: C₆H₁₂NO₃*Eu
• 分子量: 298.126
• InChiKey: UGQLLWKXTIRMKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.63
• 重原子数：
  11.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  72.42
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  三乙醇胺 、 在 吡啶 作用下， 以 四氢呋喃 为溶剂， 以96%的产率得到
  参考文献：
  名称：

  Complexes of lanthanides with triethanolamine

  摘要：

  Reactions of equimolar amounts of Cp3Er or amides [(Me3Si)(2)N](3)Ln (Ln = Y, Nd) with triethanolamine lead to the formation of insoluble products of the composition Ln(OC2H4)(3)N. Naphthalene complex of Eu(II), Cl10H8Eu(THF)(3), reacts with triethanolamine also with the formation of insoluble compound of trivalent europium Eu(OC2H4)(3)N. Erbium aminoalkoxide Er(OC2H4)(3)N actively reacts with carbon dioxide at room temperature and atmospheric pressure in THF to form the adduct Er[OC(O)OC2H4](3)N. In the reaction of triethanolamine with the excess of [(Me3Si)(2)N](3)Ln (Ln = Y, Eu) in THF soluble binuclear complexes of the composition [(Ne3Si](2)NLn(OC2H4)(3)NC(2)H(4)OLn[N(SiMe3)(2)](2)(THF) are formed. The reaction of triethanolamine with [(Me3Si)(2)N](3)Y in 3:1 ratio in THF gives the compound Y[OC2H4N(C2H4OH)(2)](3). The composition and structure of obtained complexes was established by elemental analysis and the IR and NMR spectroscopy.

  DOI：

  10.1134/s1070363212060011