2-(biphenyl-4-yl)-9,10-anthraquinone | 75534-89-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(biphenyl-4-yl)-9,10-anthraquinone
• 英文别名: 2-biphenyl-4-yl-anthraquinone；2-Biphenyl-4-yl-anthrachinon；2-(4-Phenylphenyl)anthracene-9,10-dione
• CAS: 75534-89-3
• 化学式: C₂₆H₁₆O₂
• 分子量: 360.412
• InChiKey: UIEVNSBLESZHMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(biphenyl-4-yl)-9,10-anthraquinone 、 丙二腈 在 吡啶 、 四氯化钛 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 以54%的产率得到2-(biphenyl-4-yl)-11,11,12,12-tetracyano-9,10-anthraquinodimethane
  参考文献：
  名称：

  Tetracyanoanthraquinodimethanes Having Biaryl Substituents: Synthesis, Crystal Structures, and Physical Properties

  摘要：

  具有四种芳基取代基的11,11,12,12-四氰基-9,10-蒽醌二甲烷（TCNAQ）衍生物：苯基、联苯基-4-基、噻吩-2-基和2,2'-联噻吩-5-合成并表征了其2-位上的基团。通过单晶 X 射线结构分析确定了它们的晶体结构，表明 TCNAQ 部分和供电子取代基形成供体-受体分离的柱状结构。非平面电子受体 TCNAQ 和平面供体单元的组合提供了一种提供分离柱状结构的好方法。

  DOI：

  10.1246/cl.2012.482
• 作为产物：
  描述：

  2-biphenyl-4-yl-anthracene 在 chromium(VI) oxide 作用下， 生成 2-(biphenyl-4-yl)-9,10-anthraquinone
  参考文献：
  名称：

  Buu-Hoi et al., Recueil des Travaux Chimiques des Pays-Bas, 1957, vol. 76, p. 962,967

  摘要：

  DOI：

文献信息

• SURFACE-MODIFIED INORGANIC NITRIDE, COMPOSITION, THERMALLY CONDUCTIVE MATERIAL, AND DEVICE WITH THERMALLY CONDUCTIVE LAYER
  申请人：FUJIFILM Corporation

  公开号：US20200148538A1

  公开（公告）日：2020-05-14

  A first object of the present invention is to provide a surface-modified inorganic nitride having excellent dispersibility. Furthermore, a second object of the present invention is to provide a composition, a thermally conductive material, and a device with a thermally conductive layer which contain the surface-modified inorganic nitride. The surface-modified inorganic nitride of the present invention includes an inorganic nitride, and a compound which is represented by General Formula (I) and is adsorbed onto a surface of the inorganic nitride. In General Formula (1), n represents an integer of 3 or greater. X represents an aromatic hydrocarbon ring group or an aromatic heterocyclic group. Y represents a single bond, —O—, —CO—, —CO—O—, —O—CO—, —S—, —CS—, —NR A —, —N═N—, or a divalent unsaturated hydrocarbon group. R A represents a hydrogen atom or an alkyl group. R 1 and R 2 each independently represent a substituent. Here, at least one of R 1 or R 2 represents a monovalent organic group containing a specific functional group selected from the group A of specific functional groups. In General Formula (1), a plurality of X's may be the same as or different from each other. Moreover, a plurality of Y's may be the same as or different from each other.