[Pd(o-C6H4CH2NMe2)(2-methyl-2-amino-4-iminopentane)]ClO4 | 476362-61-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Pd(o-C6H4CH2NMe2)(2-methyl-2-amino-4-iminopentane)]ClO4
• CAS: 476362-61-5
• 化学式: C₁₅H₂₆N₃Pd*ClO₄
• 分子量: 454.262
• InChiKey: WMGJJOKKPRHENT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis[(benzyldimethylamino)chloropalladium(II)] 、 氨 、 silver perchlorate 、 丙酮 以 氨 、 丙酮 为溶剂， 以627 %的产率得到[Pd(o-C6H4CH2NMe2)(2-methyl-2-amino-4-iminopentane)]ClO4
  参考文献：
  名称：

  Acetimine and 2-Methyl-2-amino-4-iminopentane Complexes of Palladium(II)

  摘要：

  By reaction between the labile complex cis-[Pd(C6F5)(2)(PhCN)(2)] and aqueous ammonia-acetone solutions the palladium complexes [Pd(C6F5)(2)L-2] [L = NH3 (1), NHCMe2 (2) and L-2 = NHC(Me)CH2C(Me-2)NH2 (3)] are obtained. The reaction product depends on the experimental conditions used. The cationic complexes [Pd(dmba)L-2]ClO4 [L = NH3 (5), NHCMe2 (6) and L-2 = NH C(Me)CH2C(Me-2)NH2 (7)] with the N,C-chelating 2-(dimethyl-aminomethyl)phenyl (dmba) ligand have been obtained by treating [(dmba)Pd(mu-Cl)(2)Pd-(dmba)] with AgClO4 in aqueous ammonia-acetone solution. The mono(acetimine) complex [Pd(dmba)(PPh3)(NHCMe2)]ClO4 (8) is obtained by a similar procedure starting from [Pd-(dmba)(PPh3)Cl]. The crystal structures of 1-3 and 6 and 7 have been determined; there is extensive hydrogen bonding (N-H...F-C or N-H...OClO3) in all the compounds.

  DOI：

  10.1021/om020434y