(dimethylamino)zirconium(IV) iodide | 452334-34-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (dimethylamino)zirconium(IV) iodide
• CAS: 452334-34-8
• 化学式: C₂H₆I₃NZr
• 分子量: 516.014
• InChiKey: GSNVNYXBDJYKPB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四(二甲氨基)锆 、 碘化锆(IV) 以 甲苯 为溶剂， 以43%的产率得到(dimethylamino)zirconium(IV) iodide
  参考文献：
  名称：

  Synthesis and Structures of Zirconium Amide−Iodide Complexes

  摘要：

  Zirconium amide-iodide complexes were synthesized for possible use as chemical vapor deposition precursors to zirconium nitride films. The series of six complexes Zr(NR2)(4)-I-n(n), (R = Me or Et; n = 1-3) was prepared by reacting Zrl(4) and Zr(NR2)(4) in hot toluene. X-ray crystallographic analyses were performed for Zr(NMe2)(3)I, Zr(NEt2)(2)I-2, and Zr(NEt2)I-3. In the solid state, Zr(NMe2)(3)I and Zr(NEt2)(2)I-2 are the discrete dimers [Zr(NMe2)(2)I(mu-NMe2)](2) and [Zr(NEt2)(2)I(mu-I)](2), and Zr(NEt2)I-3 is the polymer of dimers {[Zr(NEt2)I-2(mu-I)](2)}(n). In solution, Zr(NEt2)(3)I is proposed to be monomeric on the basis of NMR data and a molecular weight determination. The complex Zr(NEt2)(3)I is the most promising precursor candidate because of its physical properties.

  DOI：

  10.1021/ic025630b