| 897402-30-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• CAS: 897402-30-1
• 化学式: C₄₆H₃₈Br₂N₄S₄Zn
• 分子量: 1000.3
• InChiKey: LMSBGMKUFMYBJM-CZTRYZMXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三丁基(5''-己基-[2,2':5',2''-三联噻吩]-5-基)锡 、 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 以14%的产率得到
  参考文献：
  名称：

  One-dimensional porphyrin H-aggregates induced by solvent polarity

  摘要：

  A series of new porphyrin derivatives possessing the side arms of alkyl-substituted thiophene oligomer were synthesized. The effects of solvent polarity on the formation of supramolecular assembly have been studied by UV-vis absorption, fluorescence emission, and TEM measurement. The linear-shape porphyrin derivatives bearing two thiophene pentamers at meso-position showed the significant spectral changes in both blue-shift and band broadening of Soret bands which indicate the formation of a relatively larger porphyrin H-aggregate that occurred in nonpolar solvent such as n-hexane. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.09.140
• 作为产物：
  描述：

  在 zinc diacetate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以2.1 g的产率得到
  参考文献：
  名称：

  One-dimensional porphyrin H-aggregates induced by solvent polarity

  摘要：

  A series of new porphyrin derivatives possessing the side arms of alkyl-substituted thiophene oligomer were synthesized. The effects of solvent polarity on the formation of supramolecular assembly have been studied by UV-vis absorption, fluorescence emission, and TEM measurement. The linear-shape porphyrin derivatives bearing two thiophene pentamers at meso-position showed the significant spectral changes in both blue-shift and band broadening of Soret bands which indicate the formation of a relatively larger porphyrin H-aggregate that occurred in nonpolar solvent such as n-hexane. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.09.140