[Co(pyridine)(diphenyl glyoxime)2(CH2C6H4C6H4CH3)] | 1009818-60-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: [Co(pyridine)(diphenyl glyoxime)2(CH2C6H4C6H4CH3)]
• CAS: 1009818-60-3
• 化学式: C₄₇H₄₀CoN₅O₄
• 分子量: 797.859
• InChiKey: KKFYJOWUDFRKDJ-AGMWPDPBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Co(diphenylglyoximato)₂Cl(pyridine)] 、 2,2′-双(溴甲基)-1,1′-联苯 在 NaOH 、 NaBH₄ 作用下， 以 甲醇 、 乙醚 、 水 为溶剂， 生成 [Co(pyridine)(diphenyl glyoxime)2(CH2C6H4C6H4CH3)] 、 [(Co(pyridine)(diphenyl glyoxime)2)2(CH2C6H4C6H4CH2)]
  参考文献：
  名称：

  Biphenyl-Bridged Dicobaloximes: Synthesis, NMR, CV, and X-Ray Study

  摘要：

  4,4'-Disubstituted biphenyl-bridged dicobaloximes, Py(L)(2)Co-CH2-Ar-CH2-Co(L)(2)Py [L = dmgH, dpgH], have been synthesized and characterized. The cobalt-bound CH2 is diastereotopic and the dmgH (Me) shows nonequivalence in the H-1 NMR. This may occur due to atropisomerism and/or restricted rotation of the C-Ph/Co-C bond. Two X-ray structures of the biphenyl-bridged dicobaloximes, reported for the first time, show no direct or indirect interaction between the two cobaloxime units [Co(dioxime)(2)Py]. The NMR spectra and X-ray structural details complement each other. Three redox processes, Collf/coll, Co-II/Co-I, and Co-IV/Co-III, are observed in the CV study. Two cobalt centers are oxidized at different potentials as two discrete units even though these are symmetrically located with respect to each other with no interaction between them.

  DOI：

  10.1021/om7009045

文献信息

• Synthesis, Characterization, and Variable-Temperature ¹H NMR Behavior of Organo-Bridged Dicobaloximes
  作者：B. D. Gupta、V. Vijaikanth、Veena Singh

  DOI：10.1021/om034273p

  日期：2004.4.1

  Organo-bridged dicobaloximes with four different dioximes Py(L)(2)CoCH2-R-CH2Co(L)(2)Py (L = dmgH, dpgH, chgH, and gH) have been synthesized and characterized by H-1 and C-13 NMR and FAB mass spectroscopy. The cis influencing order observed in dicobaloximes is similar to the previously observed order in monocobaloximes. The cyclic voltammetric results show that an irreversible single-step two-electron reduction of Co-III to Co-I takes place. The Co-C bond in 4a cleaves during crystallization and results in the formation of o-vinylbenzyl cobaloxime. The variable-temperature H-1 NMR study suggests that the Co-C bond rotation is restricted and its magnitude depends on both the nature of the bridging ligand and the dioxime.