8-methoxy-1-(2'-aminophenyl)naphthalene | 683764-65-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-methoxy-1-(2'-aminophenyl)naphthalene
• 英文别名: 2-(8-methoxy-naphthalen-1-yl)phenylamine；2-(8-Methoxynaphthalen-1-yl)aniline
• CAS: 683764-65-0
• 化学式: C₁₇H₁₅NO
• 分子量: 249.312
• InChiKey: QHQRSNGBHBPNBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 8-methoxy-1-(2'-aminophenyl)naphthalene 在 溶剂黄146 、 sodium cyanoborohydride 作用下， 以 乙腈 为溶剂， 反应 1.0h， 以22%的产率得到8-methoxy-1-(2'-N-methylaminophenyl)naphthalene
  参考文献：
  名称：

  Synthesis of novel 1-aryl-substituted 8-methoxynaphthalenes and their tendency for atropisomerization

  摘要：

  Novel 1-aryl-substituted 8-methoxynaphthalenes were conveniently prepared by using Suzuki-Miyaura cross-coupling as a key reaction. Chemical transformations of the coupled products gave a variety of biaryls bearing various functional groups. The optical behavior of the separated enantiomers of these derivatives was also investigated by HPLC analysis. The optical resolution and determination of absolute configuration of novel binaphtyl derivative were also described. These new compounds may have some potential as mono- or bidentate ligands for metal-catalyzed chemical transformations including asymmetric induction. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.01.025
• 作为产物：
  描述：

  8-methoxy-1-(2'-nitrophenyl)naphthalene 在 盐酸 、 indium 作用下， 以 四氢呋喃 为溶剂， 反应 41.0h， 以93%的产率得到8-methoxy-1-(2'-aminophenyl)naphthalene
  参考文献：
  名称：

  Synthesis of novel 1-aryl-substituted 8-methoxynaphthalenes and their tendency for atropisomerization

  摘要：

  Novel 1-aryl-substituted 8-methoxynaphthalenes were conveniently prepared by using Suzuki-Miyaura cross-coupling as a key reaction. Chemical transformations of the coupled products gave a variety of biaryls bearing various functional groups. The optical behavior of the separated enantiomers of these derivatives was also investigated by HPLC analysis. The optical resolution and determination of absolute configuration of novel binaphtyl derivative were also described. These new compounds may have some potential as mono- or bidentate ligands for metal-catalyzed chemical transformations including asymmetric induction. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.01.025

文献信息

• TRANSITION METAL COMPLEX COMPOUND, OLEFIN POLYMERIZATION CATALYST CONTAINING THE COMPOUND, AND METHOD FOR PRODUCING OLEFIN POLYMER PERFORMED IN THE PRESENCE OF THE CATALYST
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2174928A1

  公开（公告）日：2010-04-14

  The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts. A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I') below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst.

  本发明提供了过渡金属络合物、含有该化合物的高活性烯烃低聚催化剂以及使用该催化剂的烯烃低聚工艺。 根据本发明的过渡金属络合物 [A] 由下式 (I) 或式 (I') 表示。烯烃低聚催化剂包括过渡金属配合物[A]。在本发明的烯烃低聚工艺中，烯烃在催化剂存在下进行低聚。
• TRANSITION METAL COMPLEX COMPOUND, OLEFIN OLIGOMERIZATION CATALYST CONTAINING THE COMPOUND, AND METHOD FOR PRODUCING OLEFIN OLIGOMER PERFORMED IN THE PRESENCE OF THE CATALYST
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2174928B1

  公开（公告）日：2015-03-11
• TRANSITION METAL COMPLEX COMPOUNDS, OLEFIN OLIGOMERIZATION CATALYSTS INCLUDING THE COMPOUNDS, AND PROCESSES FOR PRODUCING OLEFIN OLIGOMERS USING THE CATALYSTS
  申请人：Suzuki Yasuhiko

  公开号：US20110082325A1

  公开（公告）日：2011-04-07

  The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts. A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I′) below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst.
• US8258361B2
  申请人：——

  公开号：US8258361B2

  公开（公告）日：2012-09-04
• Synthesis of novel 1-aryl-substituted 8-methoxynaphthalenes and their tendency for atropisomerization
  作者：Seiji Yoshikawa、Jun-ichi Odaira、Yuki Kitamura、Ashutosh V Bedekar、Takumi Furuta、Kiyoshi Tanaka

  DOI：10.1016/j.tet.2004.01.025

  日期：2004.3

  Novel 1-aryl-substituted 8-methoxynaphthalenes were conveniently prepared by using Suzuki-Miyaura cross-coupling as a key reaction. Chemical transformations of the coupled products gave a variety of biaryls bearing various functional groups. The optical behavior of the separated enantiomers of these derivatives was also investigated by HPLC analysis. The optical resolution and determination of absolute configuration of novel binaphtyl derivative were also described. These new compounds may have some potential as mono- or bidentate ligands for metal-catalyzed chemical transformations including asymmetric induction. (C) 2004 Elsevier Ltd. All rights reserved.