bis(thienylphenyl)(4-bromophenyl)amine | 197654-22-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(thienylphenyl)(4-bromophenyl)amine
• 英文别名: N-(4-bromophenyl)-4-thiophen-2-yl-N-(4-thiophen-2-ylphenyl)aniline
• CAS: 197654-22-1
• 化学式: C₂₆H₁₈BrNS₂
• 分子量: 488.472
• InChiKey: NURYWXLHFRNKHG-UHFFFAOYSA-N

物化性质

• 沸点：
  623.5±55.0 °C(Predicted)
• 密度：
  1.410±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-溴-5-甲基噻吩 、 bis(thienylphenyl)(4-bromophenyl)amine 在 bis-triphenylphosphine-palladium(II) chloride magnesium 作用下， 以 乙醚 、 四氢呋喃 为溶剂， 反应 4.0h， 以46%的产率得到bis[4-(2-thienyl)phenyl][4-(5-methyl-2-thienyl)phenyl]amine
  参考文献：
  名称：

  Synthesis and Electrochemical Properties of Oligo- and Poly(thienylphenylamine)s

  摘要：

  The oxidative polymerization of tris(thienylphenyl)amine derivatives was performed in acetonitrile by electrochemical and chemical methods. Oligomers were synthesized by stepwise coupling using coupling reactions. The polymer prepared using the trifunctional monomer on a Pt electrode showed significantly better redox behavior compared to that of the linear polymeric analogue, The branching polymers exhibit conductivity of 2-6 S/cm, which is more than 1 order of magnitude greater than the analogous linear polymer. The electropolymerization of trifunctional monomers provides the formation of a large amount of redox active polymers with a large capacity (ca. 40 mC/cm(2)) and a good redox activity in the electron transfer of ferrocene on the electrode.

  DOI：

  10.1021/ma011018c
• 作为产物：
  描述：

  2-溴噻吩 、 三(4-溴苯基)胺 在 bis-triphenylphosphine-palladium(II) chloride magnesium 作用下， 以 乙醚 、 四氢呋喃 为溶剂， 反应 14.0h， 以36%的产率得到bis(thienylphenyl)(4-bromophenyl)amine
  参考文献：
  名称：

  Synthesis and Electrochemical Properties of Oligo- and Poly(thienylphenylamine)s

  摘要：

  The oxidative polymerization of tris(thienylphenyl)amine derivatives was performed in acetonitrile by electrochemical and chemical methods. Oligomers were synthesized by stepwise coupling using coupling reactions. The polymer prepared using the trifunctional monomer on a Pt electrode showed significantly better redox behavior compared to that of the linear polymeric analogue, The branching polymers exhibit conductivity of 2-6 S/cm, which is more than 1 order of magnitude greater than the analogous linear polymer. The electropolymerization of trifunctional monomers provides the formation of a large amount of redox active polymers with a large capacity (ca. 40 mC/cm(2)) and a good redox activity in the electron transfer of ferrocene on the electrode.

  DOI：

  10.1021/ma011018c

文献信息

• 一种AIE型发光材料及其制备方法
  申请人：扬州工业职业技术学院

  公开号：CN116396293A

  公开（公告）日：2023-07-07

  本发明选择[Ir(OMe)cod]2、三(五氟苯基)膦为催化剂将频哪醇硼酯溶于1,4‑二氧六环中与多种苝酰亚胺核进行反应以制备具有四个活性位点的邻羰基位的硼酯‑苝酰亚胺衍生物，然后通过一步钯催化偶联反应将三苯胺衍生物链接硼酯‑苝酰亚胺衍生物，制备具有高度对称、分子内扭曲的系列光电材料，通过对材料荧光性质的测定可知，本发明制备的材料具有红光发射波长、荧光量子产率高等优点，本发明开发的n型PDI光电材料，合成方法较简单，反应条件不苛刻，为n型光电材料的开发提供了新途径。
• Thienyl Triarylamines. Reactivity and Spectra of Cation Radicals and Dications.
  作者：Ibro Tabakovic、Yoshihito Kunugi、Augusto Canavesi、Larry L. Miller、Giovanni V. Sebastiani、George W. Francis、József Szúnyog、Bengt Långström

  DOI：10.3891/acta.chem.scand.52-0131

  日期：——

  The alpha-thienyl substituted triarylamines, bis(4-bromophenyl)-4-(2-thienyl)-phenylamine (1), (4-bromophenyl)bis-[4-(2-thienyl)phenyl]amine (2) and tris[4-(2-thienyl)phenyl]amine (3) were prepared as novel molecular systems for photoelectrical conversion. Electrochemical oxidations using solvents like hexafluoroisopropanol were performed to evaluate the stability of the corresponding cation radicals. The dimer 5,5'-bis[4-di(4-bromophenyl)amino]phenyl}-2,2'-bithiophene (1D) was prepared by an electrochemical oxidation-reduction sequence. Chemical and electrochemical oxidations of 1D were studied and UV-VIS-NIR spectra of the neutral, cation radical and dication are reported.
• CN115873013
  申请人：——

  公开号：——

  公开（公告）日：——