ethylenetetracarboxylic acid dianhydride | 15016-12-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 呋喃类
• 英文名称: ethylenetetracarboxylic acid dianhydride
• 英文别名: ethylenetetracarboxylic dianhydride；1H,3H-Furo(3,4-C)furan-1,3,4,6-tetrone；furo[3,4-c]furan-1,3,4,6-tetrone
• CAS: 15016-12-3
• 化学式: C₆O₆
• 分子量: 168.062
• InChiKey: GBASTSRAHRGUAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  乙烯-1,1,2,2-四羧酸 生成 ethylenetetracarboxylic acid dianhydride
  参考文献：
  名称：

  PATTERSON J. M.; HAIDAR N. F.; BRAUN L. L.; SMITH T. JR., J. ANAL. APPL. PYROL., 1981, 2, NO 4, 331-337

  摘要：

  DOI：

文献信息

• Microwave-assisted solid phase conversion study of Meldrum's acid to ethylenetetracarboxylic dianhydride (C6O6)
  作者：Avat (Arman) Taherpour

  DOI：10.1016/j.saa.2009.10.049

  日期：2010.1

  Utilization of microwave irradiation provides an effective method for fast synthesizing of some important compounds. Microwave-assisted solid phase is an especial class in chemical synthesis. By the use of MW-irradiation on chemicals, sometimes interesting results can be seen. The synthesis of the interesting molecule ethylenetetracarboxylic dianhydride (C6O6) was attempted with a few different methods. In this study, the microwave-assisted solid phase conversion of Meldrum's acid to ethylenetetracarboxylic dianhydride was reported. This conversion was characterized by FT-IR, GC/MS and NMR spectroscopy results. (C) 2009 Elsevier B.V. All rights reserved.
• Kiselev, V. D.; Iskhakova, G. G.; Shtyrlin, Yu. G., Russian Journal of Organic Chemistry, 1993, vol. 29, # 6.1, p. 923 - 926
  作者：Kiselev, V. D.、Iskhakova, G. G.、Shtyrlin, Yu. G.、Konovalov, A. I.

  DOI：——

  日期：——
• PATTERSON J. M.; HAIDAR N. F.; BRAUN L. L.; SMITH T. JR., J. ANAL. APPL. PYROL., 1981, 2, NO 4, 331-337
  作者：PATTERSON J. M.、 HAIDAR N. F.、 BRAUN L. L.、 SMITH T. JR.

  DOI：——

  日期：——