N,N,N',N'-tetrakis(aminopropyl)hexamethylenediamine | 78191-80-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetrakis(aminopropyl)hexamethylenediamine
• 英文别名: N,N,N',N'-tetrakis(3-aminopropyl)-1,6-hexanediamine；N,N,N',N'-tetra(3-aminopropyl)-1,6-diaminohexane；N,N,N',N'-tetrakis(3-aminopropyl)hexane-1,6-diamine
• CAS: 78191-80-7
• 化学式: C₁₈H₄₄N₆
• 分子量: 344.588
• InChiKey: JPGWXNLPJRELGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  24
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  111
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2N,4N'-dibutyl-6-chloro-2N,4N'-bis(1,2,2,6,6-tetramethylpiperidin-4-yl)-1,3,5-triazine-2,4-diamine 、 N,N,N',N'-tetrakis(aminopropyl)hexamethylenediamine 在 potassium carbonate 作用下， 以 1,3-二甲基-2-咪唑啉酮 为溶剂， 反应 16.0h， 生成 6-N-[3-[6-[bis[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]amino]propyl]amino]hexyl-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]amino]propyl]amino]propyl]-2-N,4-N-dibutyl-2-N,4-N-bis(1,2,2,6,6-pentamethylpiperidin-4-yl)-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  EP1840127

  摘要：

  公开号：
• 作为产物：
  描述：

  N,N,N',N'-tetrakis(cyanoethyl)hexamethylenediamine 在 Raney Co 氢气 作用下， 以 1,4-二氧六环 为溶剂， 180.0 ℃ 、9.0 MPa 条件下， 反应 2.5h， 生成 N,N,N',N'-tetrakis(aminopropyl)hexamethylenediamine
  参考文献：
  名称：

  EP1840127

  摘要：

  公开号：

文献信息

• Synthesis of Heterobinudear Cu(II)Ni(II) Complexes with Bis(tetraazamacrocycle)
  作者：Katsura Mochizuki、Yumiko Endoh

  DOI：10.1246/bcsj.62.936

  日期：1989.3

  A new series of heterobinudear Cu(II)Ni(II) complexes with bis(tetraazamacrocycle), i.e., 7,7′-polymethylenebis[2,12-dimethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),2,11,13,15-pentaene]copper(II)nickel(II) perchlorates with polymethylene bridges with a length of 2–6-C, were synthesized by a template reaction.

  与双（四氮杂大环），即 7,7'-聚亚甲基双[2,12-二甲基-3,7,11,17-四氮杂双环[11.3.1]十七碳化物的一系列新的异双核铜（II）Ni（II）配合物-1(17),2,11,13,15-戊烯]铜(II)镍(II)高氯酸盐与长度为2-6-C的多亚甲基桥，通过模板反应合成。
• Synthesis and Square Planar-Octahedral Equilibrium of Bismacrocyclic Dinickel(II) Complexes with Polymethylene Bridges of Various Lengths
  作者：Katsura Mochizuki、Yosihito Ikeda

  DOI：10.1246/bcsj.63.1587

  日期：1990.6

  A new series of binuclear nickel(II) complexes with bis(tetraazamacrocycle), 7,7′-polymethylenebis[3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene]dinickel(II) perchlorates with polymethylene bridges with a length of 2–6-C, was synthesized, as well as the corresponding free ligands. The dinickel(II) complexes were found to be in equilibrium between square planar and octahedral forms in

  一系列新的双核镍（II）与双（四氮杂大环）, 7,7'-聚亚甲基双[3,7,11,17-四氮杂双环[11.3.1]十七烷-1(17),13,15-三烯]配合物合成了具有长度为 2-6-C 的多亚甲基桥的高氯酸二镍 (II) 以及相应的游离配体。发现二镍 (II) 配合物在水中处于方形平面和八面体形式之间的平衡状态。随着聚亚甲基桥变短，平衡向八面体侧移动。
• Polyamine Derivative and Polyol Derivative
  申请人：Mita Naruyoshi

  公开号：US20080230743A1

  公开（公告）日：2008-09-25

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organic material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is a hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括上述任何一种化合物的有机材料稳定剂；一种稳定有机材料的方法；以及稳定的有机材料。通式（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子，烷基，烷氧基或酰基；R4是氢原子或烷基；n是3至16的整数）对于稳定有机材料免受光，热，氧，臭氧和电磁波（如X射线和γ射线）的损害非常有效。
• Polyamine derivative and polyol derivative
  申请人：BASF SE

  公开号：US08076478B2

  公开（公告）日：2011-12-13

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organic material. Compounds of the general formula: (1) (wherein X is N(R4) or an oxygen atom; R1 is an n-valent hydrocarbon group; R2 is a hydrogen atom or an alkyl; R3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括任何这些化合物的有机材料稳定剂；一种稳定有机材料的方法；以及稳定的有机材料。一般式化合物：(1)（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子，烷基，烷氧基或酰基；R4是氢原子或烷基；n是3至16的整数）对于通过光，热，氧气，臭氧和电磁波（如X射线和γ射线）的恶化稳定有机材料有效。
• POLYAMINE DERIVATIVE AND POLYOL DERIVATIVE
  申请人：MITA NARUYOSHI

  公开号：US20120053270A1

  公开（公告）日：2012-03-01

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organinc material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is an hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括任何此类化合物的有机材料稳定剂；一种稳定有机材料的方法；以及一种稳定的有机材料。通式为（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子、烷基、烷氧基或酰基；R4是氢原子或烷基；n是3到16的整数）对于通过光、热、氧、臭氧和电磁波（如X射线和γ射线）恶化的有机材料的稳定化是有效的。