Manganese(II) 2,9,16,23-tetra(nitro)phthalocyanine | 588705-85-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Manganese(II) 2,9,16,23-tetra(nitro)phthalocyanine
• 英文别名: manganese(2+);6,15,24,33-tetranitro-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene
• CAS: 588705-85-5
• 化学式: C₃₂H₁₂MnN₁₂O₈
• 分子量: 747.461
• InChiKey: CKVKZVULANKYRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Manganese(II) 2,9,16,23-tetra(nitro)phthalocyanine 在 sodiumsulfide nonahydrate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以19.84%的产率得到Manganese(II) 2,9,16,23-tetra(amino)phthalocyanine
  参考文献：
  名称：

  金属酞菁化学改性碳纳米管对锂/SOCl2电池具有优异的电催化活性

  摘要：

  Carbon nanotubes (CNTs)-templated metal phthalocyanines (MPc) (M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II)) assemblies (CNTs-CONH-MPc) were synthesized and characterized by IR, XRD, SEM, XPS. The lithium-thionyl chloride (Li/SOCl2) cells using CNTs-CONH-MPc as catalysts showed excellent performance, which the capacities increased by 15.44-88.49%, and the initial voltages improved to 3.09-3.22 V. The sequence of the electrochemical catalytic performance of CNTs-CONH-MPc was ranked by central metal ion: Co > Ni > Mn > Fe > Cu > Zn. Based on cyclic voltammetry measurements, the reasonable mechanism is proposed and the role of catalyst is verified. The modified CNTs by MPc greatly promoted the electronic transmission, which significantly improved the performance and the initial voltage of Li/SOCl2 battery. (C) 2017 The Electrochemical Society. All rights reserved.

  DOI：

  10.1149/2.0611706jes
• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 4-硝基邻苯二甲酰亚胺 在 ammonium dimolybdate 、 氯化铵 、 尿素 作用下， 反应 4.0h， 以20.87%的产率得到Manganese(II) 2,9,16,23-tetra(nitro)phthalocyanine
  参考文献：
  名称：

  金属酞菁化学改性碳纳米管对锂/SOCl2电池具有优异的电催化活性

  摘要：

  Carbon nanotubes (CNTs)-templated metal phthalocyanines (MPc) (M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II)) assemblies (CNTs-CONH-MPc) were synthesized and characterized by IR, XRD, SEM, XPS. The lithium-thionyl chloride (Li/SOCl2) cells using CNTs-CONH-MPc as catalysts showed excellent performance, which the capacities increased by 15.44-88.49%, and the initial voltages improved to 3.09-3.22 V. The sequence of the electrochemical catalytic performance of CNTs-CONH-MPc was ranked by central metal ion: Co > Ni > Mn > Fe > Cu > Zn. Based on cyclic voltammetry measurements, the reasonable mechanism is proposed and the role of catalyst is verified. The modified CNTs by MPc greatly promoted the electronic transmission, which significantly improved the performance and the initial voltage of Li/SOCl2 battery. (C) 2017 The Electrochemical Society. All rights reserved.

  DOI：

  10.1149/2.0611706jes