Methyl-sec.butylketon-thiosemicarbazon | 6318-50-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Methyl-sec.butylketon-thiosemicarbazon
• 英文别名: metylisobutylketone thiosemicarbazone；isobutylmethylketone thiosemicarbazone；(3-Methylpentan-2-ylideneamino)thiourea
• CAS: 6318-50-9
• 化学式: C₇H₁₅N₃S
• mdl: MFCD21101378
• 分子量: 173.282
• InChiKey: UNNYJSFTDNGZQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.714
• 拓扑面积：
  82.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Methyl-sec.butylketon-thiosemicarbazon 、 cobalt(II) chloride 在 NH₃ 作用下， 以 乙醇 、 水 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Co(II), Ni(II), Cu(II) and Zn(II) Complexes of Thiosemicarbazones

  摘要：

  Bis-chelates of Co(II) Ni(II), Cu(II) and Zn(II) with the thiol form of methylisopropylketone and methylisobutylketone thiosemicarbazones have been synthesized and characterised by analytical, conductivity, magnetic moment, infrared, electronic and ESR spectral studies. Based on analytical data the stoichiometry of the complexes has been found to be 1:2. The conductivity data show that all the complexes are non-electrolytes, The Co(II) complexes were found to have polymeric octahedral geometry. The Ni(II) and Zn(II) complexes are diamagnetic and were found to have square-planar and tetrahedral geometry, respectively. Square-planar geometry has also been suggested for the paramagnetic Cu(II) complexes.

  DOI：

  10.1080/00945719608004251

文献信息

• Chandra, S.; Gupta, L.; Tyagi, V. P., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 537 - 550
  作者：Chandra, S.、Gupta, L.、Tyagi, V. P.

  DOI：——

  日期：——
• Co(II), Ni(II), Cu(II) and Zn(II) Complexes of Thiosemicarbazones
  作者：S. Chandra、Laveena Gupta、Virendra P. Tyagi

  DOI：10.1080/00945719608004251

  日期：1996.1

  Bis-chelates of Co(II) Ni(II), Cu(II) and Zn(II) with the thiol form of methylisopropylketone and methylisobutylketone thiosemicarbazones have been synthesized and characterised by analytical, conductivity, magnetic moment, infrared, electronic and ESR spectral studies. Based on analytical data the stoichiometry of the complexes has been found to be 1:2. The conductivity data show that all the complexes are non-electrolytes, The Co(II) complexes were found to have polymeric octahedral geometry. The Ni(II) and Zn(II) complexes are diamagnetic and were found to have square-planar and tetrahedral geometry, respectively. Square-planar geometry has also been suggested for the paramagnetic Cu(II) complexes.