(HNEt3)(i-Pr2PSe2) | 943606-97-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (HNEt3)(i-Pr2PSe2)
• CAS: 943606-97-1
• 化学式: C₆H₁₄PSe₂*C₆H₁₆N
• 分子量: 377.271
• InChiKey: USGJAXCKTCVGBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.07
• 重原子数：
  16.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  (HNEt3)(i-Pr2PSe2) 、 zinc(II) chloride 以 甲醇 、 水 为溶剂， 以73.6%的产率得到
  参考文献：
  名称：

  Novel inorganic rings and materials deposition

  摘要：

  This paper discusses the use of two relative unexploited classes of molecules based on imino-dialkylphosphinate [(EPR2)(2)NH] (E = Se or Te) and dialkyldiselenophosphinate [HNEt3][R2PSe2] and subsequently, their potential for the deposition of useful materials as either thin films or nanoparticles. The structural properties of the materials obtained were elucidated by means of X-ray powder diffraction, scanning electron microscope and transmission electron microscope. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.11.043
• 作为产物：
  描述：

  氯二异丙基膦 、 三乙胺 在 三乙基硅烷 、 selenium 作用下， 以 甲苯 为溶剂， 反应 26.0h， 以89%的产率得到(HNEt3)(i-Pr2PSe2)
  参考文献：
  名称：

  Novel inorganic rings and materials deposition

  摘要：

  This paper discusses the use of two relative unexploited classes of molecules based on imino-dialkylphosphinate [(EPR2)(2)NH] (E = Se or Te) and dialkyldiselenophosphinate [HNEt3][R2PSe2] and subsequently, their potential for the deposition of useful materials as either thin films or nanoparticles. The structural properties of the materials obtained were elucidated by means of X-ray powder diffraction, scanning electron microscope and transmission electron microscope. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.11.043

文献信息

• Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes
  作者：Arunkumar Panneerselvam、Chinh Q. Nguyen、John Waters、Mohammad A. Malik、Paul O'Brien、James Raftery、Madeleine Helliwell

  DOI：10.1039/b802012d

  日期：——

  The complexes [Ni(SePiPr2)2N}2] (1), [Ni(Se2PiPr2)2] (2), and [Co(Se2PiPr2)2] (4) were synthesised and the X-ray single crystal structures of (1) and (2) were determined. Thin films of nickel selenide, cobalt selenide and cobalt phosphide have been deposited by the chemical vapour deposition method using imidodiselenophosphinato-nickel(II) (1), -cobalt(II) [Co(SePiPr2)2N}2] (3), diselenophosphinato-nickel(II) (2), -cobalt(II) (4) and diselenocarbamato-nickel(II) [Ni(Se2CNEt2)2] (5), and -cobalt(III) [Co(Se2CNEt2)3] (6) precursors.

  合成了配合物 [Ni(SePiPr2)2N}2] (1)、[Ni(Se2PiPr2)2] (2) 和 [Co(Se2PiPr2)2] (4)，并确定了 (1) 和 (2) 的 X 射线单晶结构。通过化学气相沉积法，利用咪唑二硒磷酸镍(II) (1)、-钴(II) [Co(SePiPr2)2N}2] (3)、二硒磷酸镍(II) (2)、-钴(II) (4) 和二硒氨基镍(II) [Ni(Se2CNEt2)2] (5) 以及 -钴(III) [Co(Se2CNEt2)3] (6) 前驱体沉积了镍硒化物、钴硒化物和钴磷化物的薄膜。
• Synthesis of the nickel selenophosphinates [Ni(Se2PR2)2] (R = iPr, tBu and Ph) and their use as single source precursors for the deposition of nickel phosphide or nickel selenide nanoparticles
  作者：Weerakanya Maneeprakorn、Chinh Q. Nguyen、Mohammad A. Malik、Paul O'Brien、James Raftery

  DOI：10.1039/b816903a

  日期：——

  Nickel phosphide (Ni2P and Ni12P5) or nickel selenide (NiSe) nanoparticles were prepared from the single molecule precursor, dialkyldiselenophosphinato nickel(II), [Ni(Se2PR2)2] (R = iPr, tBu and Ph) by thermolysis in trioctylphosphine oxide (TOPO) or hexadecylamine (HDA). The chemical composition of these nanoparticles depends on the precursors, capping agents, and reaction temperature.

  从单分子前驱体双烷基二硒膦酸镍(II)，[Ni(Se2PR2)2]（R = iPr, tBu 和 Ph）通过在三辛基膦氧化物（TOPO）或十六烷胺（HDA）中的热分解制备了镍磷化物（Ni2P 和 Ni12P5）或镍硒化物（NiSe）纳米颗粒。这些纳米颗粒的化学成分取决于前驱体、包覆剂和反应温度。