[[Ni(II)(N,N'-bis(3-aminopropyl)-1,2-ethylenediamine)(μ1,5-dicyanamide)](perchlorate)]n | 952116-69-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [[Ni(II)(N,N'-bis(3-aminopropyl)-1,2-ethylenediamine)(μ1,5-dicyanamide)](perchlorate)]n
• CAS: 952116-69-7
• 化学式: C₂N₃*C₈H₂₂N₄*ClO₄*Ni
• 分子量: 398.472
• InChiKey: XOYNUCSUQDGRKS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II) perchlorate hexahydrate 、 N,N-二(3-氨丙基)乙基乙胺 、 sodium dicyanamide 以 水 、 N,N-二甲基甲酰胺 为溶剂， 以65%的产率得到[[Ni(II)(N,N'-bis(3-aminopropyl)-1,2-ethylenediamine)(μ1,5-dicyanamide)](perchlorate)]n
  参考文献：
  名称：

  Synthesis, crystal structures and magnetic properties of three Ni(II) complexes having NiN4 core with argentocyanide, terephthalate and dicyanamide ions: From discrete molecule to a helical network

  摘要：

  This work describes the synthesis and X-ray crystallographic characterization of three nickel(II) complexes [Ni(3,2,3-tet){Ag(CN)(2)}(2)] (1), [Ni(3,2,3-tet)(mu-tp)](n)center dot 1.5nH(2)O (2) and {[Ni(3,2,3-tet)(mu(1.5)-dca)](ClO4)}(n)(3) where 3,2,3-tet = N,N'-bis(3-aminopropyl)-1,2-ethylene-diamine, tp = terephthalate and dca = dicyanamide. Compound I is a heterotrinuclear discrete distorted octahedral molecule whereas compound 2 forms a ID polymeric network and an extended 21) network is formed by intermolecular hydrogen bonding. Interestingly, two adjacent ID chains execute a novel double-helical network constructed by Ni(II) and the bridging dca ligand in compound 3. The variable temperature magnetic susceptibility measurements for compounds 2 and 3 were also carried out. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.03.040