nickel(II) tetra-N-methyl-2,3-pyridinoporphyrazine | 23272-68-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: nickel(II) tetra-N-methyl-2,3-pyridinoporphyrazine
• 英文别名: nickel(II) tetrapyridinoporphyrazine；NiTAP；Ni tetrapyridinoporphyrazine
• CAS: 23272-68-6
• 化学式: C₂₈H₁₂N₁₂Ni
• 分子量: 575.174
• InChiKey: AFACZURFRKJFOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  nickel(II) tetra-N-methyl-2,3-pyridinoporphyrazine 在 氯化亚砜 、 lithium tetrachloroaluminate 作用下， 生成 NiTAP*SOCl2
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014
• 作为产物：
  描述：

  尿素 、 nickel dichloride 、 2,3-吡啶二甲酸 在 ammonium molybdate NaOH 、 H₂SO₄ 作用下， 生成 nickel(II) tetra-N-methyl-2,3-pyridinoporphyrazine
  参考文献：
  名称：

  Conductivity of reduced metallo-tetra-N-methyl-2,3-pyridinoporphyrazine complexes

  摘要：

  DOI：

  10.1016/s0020-1693(00)80294-7
• 作为试剂：
  描述：

  氯化亚砜 在 nickel(II) tetra-N-methyl-2,3-pyridinoporphyrazine LiAlCl₄ 作用下， 以 水 为溶剂， 生成 二氧化硫 、 sulfur
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014

文献信息

• Design and synthesis of nickel tetra‐2,3‐pyridiniumporphyrazinato trinitromethanide as an influential catalyst and its application in the synthesis of 1,2,4-triazolo based compounds
  作者：Mohammad Dashteh、Saeed Baghery、Mohammad Ali Zolfigol、Ardeshir Khazaei、Sajjad Makhdoomi、Maliheh Safaiee、Jamshid Rakhtshah、Yadollah Bayat、Asiye Asgari

  DOI：10.1016/j.jpcs.2021.110322

  日期：2022.1

  facile and benign syntheses of [1,2,4]triazolo[5,1-b]quinazolines and [1,2,4]triazolo[1,5-b]pyrimidines were studied using novel nickel tetra‐2,3‐pyridiniumporphyrazinato trinitromethanide [Ni(TPPAH)][C(NO2)3]4 as an efficient catalyst. The desired products were synthesized under solvent-free conditions using 10 mg of [Ni(TPPAH)][C(NO2)3]4 as a catalyst at 80 °C. The morphology and structure of [Ni(TPPAH)][C(NO2)3]4

  [1,2,4]三唑并[5,1- b ]喹唑啉和[1,2,4]三唑并[1,5- b ]嘧啶的简便和良性合成研究使用新型四-2,3-镍吡啶鎓四氮杂三硝基甲烷[Ni(TPPAH)][C(NO 2 ) 3 ] 4作为一种有效的催化剂。在无溶剂条件下使用 10 mg [Ni(TPPAH)][C(NO 2 ) 3 ] 4作为催化剂在 80 °C下合成所需产物。[Ni(TPPAH)][C(NO 2 ) 3 ] 4的形貌和结构使用多种技术进行了研究和表征。产物在反应时间短的情况下具有良好至极好的产率。所提供的催化剂被简单地回收和再利用。部分获得的产品（10 件）为首次报道。