(4Z,9Z)-1,3,6,8(1,4),2,7(1,3)-hexabenzenacyclodecaphane-4,9-diene | 754991-13-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (4Z,9Z)-1,3,6,8(1,4),2,7(1,3)-hexabenzenacyclodecaphane-4,9-diene
• CAS: 754991-13-4
• 化学式: C₄₀H₂₈
• 分子量: 508.662
• InChiKey: QQDXRIXFWGSDBA-XOHWUJONSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.42
• 重原子数：
  40.0
• 可旋转键数：
  0.0
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  (4Z,9Z)-1,3,6,8(1,4),2,7(1,3)-hexabenzenacyclodecaphane-4,9-diene 在 铂 氢气 作用下， 以 乙酸乙酯 为溶剂， 以98%的产率得到41.$3,41'.43'-Diethylen-di-m-terphenyl
  参考文献：
  名称：

  2′-Substituted meta-terphenyls as building blocks for cyclophanes with intra-annular functionality

  摘要：

  2'-Substituted m-terphenyls containing chloromethyl and/or thiomethyl groups at the 4,4'' or 3,3'' positions are used as building blocks for cyclophanes with intra-annular functionality. Syntheses are short and yields are good. The methodology, capable of wide structural variation, has been adapted to bi- and tricyclic cyclophanes.

  DOI：

  10.1016/0040-4020(94)01016-s
• 作为产物：
  描述：

  在 potassium tert-butylate 、 trimethoxonium tetrafluoroborate 作用下， 生成 (4Z,9Z)-1,3,6,8(1,4),2,7(1,3)-hexabenzenacyclodecaphane-4,9-diene
  参考文献：
  名称：

  2′-Substituted meta-terphenyls as building blocks for cyclophanes with intra-annular functionality

  摘要：

  2'-Substituted m-terphenyls containing chloromethyl and/or thiomethyl groups at the 4,4'' or 3,3'' positions are used as building blocks for cyclophanes with intra-annular functionality. Syntheses are short and yields are good. The methodology, capable of wide structural variation, has been adapted to bi- and tricyclic cyclophanes.

  DOI：

  10.1016/0040-4020(94)01016-s

文献信息

• Synthesis, complexation studies and biological applications of some novel stilbenophanes, indolophanes and bisindolostilbenophanes via McMurry coupling
  作者：Perumal Rajakumar、Merikapudi Gayatri Swaroop、S. Jayavelu、K. Murugesan

  DOI：10.1016/j.tet.2006.09.078

  日期：2006.12

  Various types of stilbenophanes, indolophanes and bisindolostilbenophanes were synthesized by intra-, inter- and tandem intra-, intermolecular McMurry coupling. Some of the indolophanes and bisindolostilbenophanes exhibited significant activity against the growth of various bacteria. Complexation of some of the cyclophanes with TCNQ has also been studied. (c) 2006 Elsevier Ltd. All rights reserved.
• The use of McMurry coupling for the synthesis of indolophanes and cis-stilbenophanes
  作者：Perumal Rajakumar、Merikapudi Gayatri Swaroop

  DOI：10.1016/j.tetlet.2004.06.020

  日期：2004.8

  Treatment of 2 equiv of indole-3-aidehyde with o, m, p-xylyl, 2,5-dimethoxy-p-xylyl dibromides and 4,4'-bis(bromomethyl)-1,1'-biphenyl gave the bisalkylated products, which underwent McMurry coupling with low valent titanium to give indolophanes. Various cis-stilbenophanes with m-terphenyl building blocks were also synthesized by application of the McMurry coupling technique. (C) 2004 Elsevier Ltd. All rights reserved.