2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone | 76767-19-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone
• 英文别名: methyl N-[(2-hydroxyphenyl)methylideneamino]-N'-phenylcarbamimidothioate
• CAS: 76767-19-6
• 化学式: C₁₅H₁₅N₃OS
• 分子量: 285.37
• InChiKey: JLNIRHVYXIJJQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  82.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis(acetylacetonato)dioxidomolybdenum(VI) 、 2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone 以 not given 为溶剂， 以35%的产率得到[dioxomolybdenum(VI)(2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone(-2H))]
  参考文献：
  名称：

  Dioxomolybdenum(VI) complexes of 2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone

  摘要：

  Mixed ligand complexes of dioxomolybdenum(VI) with 2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone (H2L) were prepared with the formula [MoO2(L)D] (D = H,O, methyl, n-butyl, and n-undecyl alcohol, DMF, DMSO, pyridine, 4-picoline, and 3,5-lutidine). The compounds were characterized by elemental analysis, IR and H-1 NMR spectroscopy. The thermal decomposition of the compounds were investigated by using TGA, DTG, and DTA methods in air, and the thermal behavior depending on the second ligand molecule was discussed. A single crystal of the DMF coordinated complex was studied by X-ray diffractometry.

  DOI：

  10.1134/s1070328407110097

文献信息

• Bourosh, P. N.; Gerbeleu, N. V.; Revenko, M. D., Russian Journal of Inorganic Chemistry, <hi>1987</hi>, vol. 32, p. 1446 - 1450
  作者：Bourosh, P. N.、Gerbeleu, N. V.、Revenko, M. D.、Simonov, Yu. A.、Bel'skii, V. K.、Byrtosu, N. I.

  DOI：——

  日期：——