7-(5-(tributylstannyl)thiophen-2-yl)-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine | 1192340-29-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 7-(5-(tributylstannyl)thiophen-2-yl)-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine
• 英文别名: 9,9-dihexyl-N,N-diphenyl-7-(5-(tributylstannyl)thiophen-2-yl)-9H-fluoren-2-amine
• CAS: 1192340-29-6
• 化学式: C₅₃H₇₁NSSn
• 分子量: 872.929
• InChiKey: QAJNZHOUOUAANI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.15
• 重原子数：
  56.0
• 可旋转键数：
  24.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2,6-二溴-N,N'-双(2-乙基己基)-1,8:4,5-萘四甲酰基二酰亚胺 、 7-(5-(tributylstannyl)thiophen-2-yl)-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine 在 bis-triphenylphosphine-palladium(II) chloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以80%的产率得到4,9-bis(5-(6-(diphenylamino)-9-ethyl-9H-carbazol-3-yl)thiophen-2-yl)-2,7-bis(2-ethylhexyl) benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone
  参考文献：
  名称：

  Synthesis and characterization of naphthalene diimide (NDI)-based near infrared chromophores with two-photon absorbing properties

  摘要：

  A new series of 2,7-bis-(2-ethylhexyl)-benzo[lmn][3,8]-phenanthroline-1,3,6,8-tetraone (NDI) based pseudo-quadrupolar molecules (1-6) is presented and their two-photon absorption (2PA) cross-sections measured with the Z-scan method. The spectral properties of these compounds can be fine-tuned via modification of the donor segments. The corresponding 2PA cross-section (sigma(2)) values at the most readily available 800 nm excitation range from 229 +/- 15 to 1092 +/- 59 GM owing to differences in conjugation length and/or position of substitution. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.09.041

文献信息

• BODIPY dyes with β-conjugation and their applications for high-efficiency inverted small molecule solar cells
  作者：Hsin-Yu Lin、Wei-Ching Huang、Yung-Chung Chen、Hsien-Hsin Chou、Chih-Yu Hsu、Jiann T. Lin、Hao-Wu Lin

  DOI：10.1039/c2cc34286c

  日期：——

  Small molecule BODIPY dyes incorporating conjugated substituents at the β sites have been synthesized. Solution processed inverted bulk heterojunction cells were fabricated from the blends of the dyes and PC71BM. The cells exhibited very high open-circuit voltages (>0.9 V) and a high conversion efficiency of 3.22% has been achieved.

  我们合成了在δ位点加入共轭取代基的小分子 BODIPY 染料。利用这些染料和 PC71BM 的混合物制造出了溶液处理的倒装体异质结电池。这种电池的开路电压非常高（大于 0.9 V），转换效率高达 3.22%。
• Dibenzo[<i>f</i>,<i>h</i>]thieno[3,4-<i>b</i>] quinoxaline-Based Small Molecules for Efficient Bulk-Heterojunction Solar Cells
  作者：Marappan Velusamy、Jen-Hsien Huang、Ying-Chan Hsu、Hsien-Hsin Chou、Kuo-Chuan Ho、Pei-Lun Wu、Wei-Hau Chang、Jiann T. Lin、Chih-Wei Chu

  DOI：10.1021/ol9019953

  日期：2009.11.5

  Two isomeric compounds (1 and 2) containing-a dibenzo[f,h]thieno[3,4-b]quinoxaline core and two peripheral arylamines were synthesized. Solution-processed bulk heterojunction (BHJ) solar cells based on these sensitizers and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) are reported. The cell fabricated from 1/67 wt % of PCBM exhibited a high power conversion efficiency of 1.70% and an external quantum yield of 55%. The film of the cell was found to have balanced electron and hole mobility and good film morphology.