1,5-dihydro-2,4,6,8-tetramethyl-s-indacene | 392245-47-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 1,5-dihydro-2,4,6,8-tetramethyl-s-indacene
• 英文别名: 2,4,6,8-Tetramethyl-1,5-dihydro-s-indacene
• CAS: 392245-47-5
• 化学式: C₁₆H₁₈
• 分子量: 210.319
• InChiKey: YUDYCAQXWHBLMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,5-dihydro-2,4,6,8-tetramethyl-s-indacene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Preparation and ESR characterization of polyalkyl-s-indacenyl anion-radicals from polyalkyl-1,5-dilithio-s-indacenes

  摘要：

  Polyalkyl-(or chloropolyalkyl)-s-indacenyl anion radicals were obtained from the organodilithium derivatives of the corresponding substituted-1,5-dihydro-s-indacenes by three different methods: (i) UV photolysis, (ii) oxidation by a ferrocenium salt, (iii) single electron transfer reaction from an electron rich olefin. The last reaction (iii) involves transient formation of an unstable polyalkyl-lithio-s-indacenyl imidazolidinium salt. The same salt, obtained by another way by reacting 1,3-dimethylimidazolidinium chloride with the polyalkyl-1,5-dilithio-s-indacene, also leads to the corresponding lithium polyalkyl-s-indacenyl anion radical. All lithium polyalkyl-s-indacenyl anion radicals studied were characterized from their ESR spectra. They present a characteristic symmetrical spin distribution. On the contrary a Rhodium-COD polyalkyl-s-indacene radical presents a non symmetrical spin distribution. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.10.002

文献信息

• From polysubstituted 1,5-dihydro-s-indacene lithium derivatives to polysubstituted hydro-s-indacenyl radicals by a new method involving a single electron transfer from an electron rich olefin
  作者：N. Katir、P. Rivière、M. Rivière-Baudet、A. Castel、C. Adams、D. MacLeod Carey、P. Aguirre-Etcheverry、I. Chavez、J.M. Manriquez、E. Diaz、M. Dahrouch

  DOI：10.1016/j.ica.2010.05.029

  日期：2010.11

  Abstract Polyalkyl-hydro- s -indacenyl radicals were obtained from the corresponding polyalkyl-hydro- s -indacenylmonolithium derivatives using a monoelectronic transfer from an electron rich olefin: 1,1′,3,3′-tetramethyl-2,2′-bisimidazolidine (ERO). The reaction involves the transient formation of a polyalkyl-hydro- s -indacenylimidazolidinium salt. The same salt was obtained by another way, reacting

  摘要通过从富电子烯烃：1,1'，3,3'-四甲基-2,2'-双亚咪唑烷中进行单电子转移，从相应的聚烷基-s-茚满基单锂衍生物中获得了聚烷基-s-茚满烯基。 （ERO）。该反应涉及聚烷基-氢-s-吲哚基咪唑啉鎓盐的瞬时形成。通过另一种方法，使咪唑啉鎓氯化物与聚烷基-氢-茚并茚基锂反应，获得了相同的盐，并且还生成了相应的聚烷基-氢-茚并茚基。所有研究的聚烷基-氢-s-茚基自由基均表现出不对称的自旋分布，并且在ESR中的超精细偶联小于在类似的芳香族自由基阴离子中通常观察到的偶联。他们是从其二聚产物中鉴定出来的，也可以通过捕获2,4，6-三叔丁基亚硝基苯。还研究了铑配合物自由基类似物。
• New mono and bimetallic iron complexes derived from partially methylated s-indacene. Evidence of a trinuclear iron s-indacene complex
  作者：César Morales-Verdejo、Iván Martínez-Díaz、Christopher Adams、Juan Felipe Araneda、Luciano Oehninger、Desmond Mac-Leod Carey、Alvaro Muñoz-Castro、Ramiro Arratia-Pérez、Ivonne Chávez、Juan Manuel Manríquez

  DOI：10.1016/j.poly.2013.11.023

  日期：2014.2

  The preparation and characterization of new mono- and multinuclear iron complexes derived from s-indacene partially alkylated has been achieved by the development of rational synthetic routes. The synthesis of the new multimetallic complexes are based on the employment of 1,5-dihydro-2,4,6, 8-tetramethyl-s-indacene (Ic'H-2) as ligand to obtain two monometallic complexes, namely, [Cp*-Fe-(eta(5)-2,4,6,8-tetramethyl-5-hydro-s-indacenide)] (1), and [Fe-bis(eta(5)-2,4,6,8-tetramethyl-5-hydro-s-indacenide)] (2) (Cp* = pentamethylcyclopentadiene), as well as, the new bimetallic [Cp*Fe-(mu:eta(5):eta(5)-2,4,6,8-tetramethyl-s-indaceneiide)-FeCp*] (3) and trimetallic [Fe-bisCp*Fe-(mu:eta(5):eta(5)-2,4,6,8-tetramethyl-s-indaceneiide)}] (4) complexes. All complexes here reported were characterized by means of H-1, C-13 NMR, mass spectrometry, elemental analysis, together with cyclic voltammetry. In addition, these complexes have been studied by DFT methods in order to gain further knowledge about its electronic structure. In addition, the possibility to generate organometallic polymers employing the complexes here reported, is proposed theoretically with the study of an oligomer titled as [Cp*(Fe(Ic')}(4)FeCp*], 6(t). (C) 2013 Elsevier Ltd. All rights reserved.