1,2,3,4-tetrahydro-naphthalene-1,8-dicarboxylic acid dimethyl ester | 42025-46-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2,3,4-tetrahydro-naphthalene-1,8-dicarboxylic acid dimethyl ester
• 英文别名: 1,2,3,4-Tetrahydro-naphthalin-1,8-dicarbonsaeure-dimethylester；Dimethyl 1,2,3,4-tetrahydronaphthalene-1,8-dicarboxylate；dimethyl 1,2,3,4-tetrahydronaphthalene-1,8-dicarboxylate
• CAS: 42025-46-7
• 化学式: C₁₄H₁₆O₄
• 分子量: 248.279
• InChiKey: NRWGZEVJDVGPKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,8-萘二甲酸二甲酯 在 溶剂黄146 、 铂 作用下， 生成 1,2,3,4-tetrahydro-naphthalene-1,8-dicarboxylic acid dimethyl ester
  参考文献：
  名称：

  Casares; Ranedo, Anales de la Real Sociedad Espanola de Fisica y Quimica, vol. 20, p. 525

  摘要：

  DOI：

文献信息

• OXYGEN-ABSORBING RESIN COMPOSITION AND OXYGEN-ABSORBING MOLDED ARTICLE USING SAME AND MULTILAYER BODY, CONTAINER, INJECTION-MOLDED ARTICLE AND MEDICAL CONTAINER USING THESE
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20140308405A1

  公开（公告）日：2014-10-16

  A novel oxygen-absorbing resin composition is not responsive to a metal detector, produces no odor after absorption of oxygen and has excellent oxygen-absorbing performance, and an oxygen-absorbing molded article, and a multilayer body, container, injection-molded article and medical container. Further provided are an oxygen-absorbing resin composition etc. having excellent oxygen-absorbing performance in a wide range of humidity conditions from low to high humidity. The oxygen-absorbing resin composition is an oxygen-absorbing resin composition containing a polyester compound and a transition metal catalyst, in which the polyester compound has at least one constituent unit having a tetralin ring. Furthermore, the oxygen-absorbing molded article of the present invention is formed by molding the oxygen-absorbing resin composition into a film form or a sheet form. Moreover, the multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition of the present invention.

  一种新型的吸氧树脂组合物，不会对金属探测器产生反应，在吸收氧气后不产生异味，具有优异的吸氧性能，以及一种吸氧成型物品，多层体，容器，注塑成型物品和医疗容器。此外，还提供了一种在从低湿度到高湿度的广泛湿度条件下具有优异吸氧性能的吸氧树脂组合物等。该吸氧树脂组合物是含有聚酯化合物和过渡金属催化剂的吸氧树脂组合物，其中聚酯化合物至少具有一个四氢萘环的组分单元。此外，本发明的吸氧成型物品是通过将吸氧树脂组合物成型为膜状或片状形成的。此外，本发明的多层体，容器，注塑成型物品，医疗容器等是使用本发明的吸氧树脂组合物获得的。
• OXYGEN ABSORBENT COMPOSITION
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20160031628A1

  公开（公告）日：2016-02-04

  The oxygen absorbent composition of the present invention at least contains a polyester oligomer containing a constitutional unit having a predetermined tetralin ring and a transition metal catalyst. It is preferable that the oxygen absorbent composition of the present invention further contains a thermoplastic resin.

  本发明的氧气吸收剂组合物至少包含一种聚酯寡聚体，其中包含具有预定四氢萘环的结构单元和过渡金属催化剂。本发明的氧气吸收剂组合物最好还包含热塑性树脂。
• OXYGEN ABSORBER COMPOSITION
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2965808A1

  公开（公告）日：2016-01-13

  The oxygen absorbent composition of the present invention at least contains a polyester oligomer containing a constitutional unit having a predetermined tetralin ring and a transition metal catalyst. It is preferable that the oxygen absorbent composition of the present invention further contains a thermoplastic resin.

  本发明的吸氧剂组合物至少含有一种聚酯低聚物，该聚酯低聚物含有一个具有预定四萘环的结构单元和一种过渡金属催化剂。本发明的吸氧剂组合物最好还含有热塑性树脂。
• Oxygen-absorbing resin composition and oxygen-absorbing molded article using same and multilayer body, container, injection-molded article and medical container using these
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10035129B2

  公开（公告）日：2018-07-31

  Oxygen-absorbing resin composition, not responsive to a metal detector, producing no odor after absorption of oxygen and has excellent oxygen-absorbing performance in a wide range of humidity conditions from low to high humidity. An oxygen-absorbing molded article, and a multilayer body, container, injection-molded article and medical containers also provided. The oxygen absorbing resin composition contains a polyester, comprising at least one constituent unit having a tetralin ring component compound, a transition metal catalyst, and a catalyst for producing the polyester. The oxygen-absorbing molded article of the present invention can be formed by molding the oxygen-absorbing resin composition into a film or a sheet. The multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition.

  吸氧树脂组合物，对金属探测器无反应，吸氧后不产生气味，在从低湿度到高湿度的广泛湿度条件下具有优异的吸氧性能。此外，还提供了一种吸氧模塑制品以及多层主体、容器、注塑制品和医疗容器。吸氧树脂组合物包含一种聚酯，其中至少一个组成单元具有四萘环组分化合物、一种过渡金属催化剂和一种用于生产聚酯的催化剂。本发明的吸氧模压制品可通过将吸氧树脂组合物模压成薄膜或片材而形成。本发明的多层体、容器、注塑制品、医用容器等都是通过使用本发明的吸氧树脂组合物获得的。
• Oxygen-absorbing multilayer body, oxygen-absorbing container, oxygen-absorbing airtight container, oxygen-absorbing push-through pack, and storage method using same
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10035640B2

  公开（公告）日：2018-07-31

  Provided is an oxygen-absorbing multilayer body including an oxygen-absorbing layer containing an oxygen-absorbing composition and a thermoplastic resin layer containing a thermoplastic resin (b), wherein the oxygen-absorbing composition includes at least one compound having a tetralin ring represented by Formula (1), a transition metal catalyst, and a thermoplastic resin (a).

  本发明提供了一种吸氧多层体，包括含有吸氧组合物的吸氧层和含有热塑性树脂（b）的热塑性树脂层，其中吸氧组合物包括至少一种具有式（1）表示的四萘环的化合物、过渡金属催化剂和热塑性树脂（a）。