[Zn(N,N'-bis(3-methoxysalicylidene)-(R)-2,2-diamine-1,1'-binaphthyl)(H2O)] | 1096533-42-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Zn(N,N'-bis(3-methoxysalicylidene)-(R)-2,2-diamine-1,1'-binaphthyl)(H2O)]
• CAS: 1096533-42-4
• 化学式: C₃₆H₂₈N₂O₅Zn
• 分子量: 634.019
• InChiKey: YEJXRZHTTZBCMZ-XIDIDSRISA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  neodymium(III) nitrate hexahydrate 、 [Zn(N,N'-bis(3-methoxysalicylidene)-(R)-2,2-diamine-1,1'-binaphthyl)(H2O)] 、 N,N-二甲基甲酰胺 以 乙醇 为溶剂， 以61%的产率得到[Zn(N,N'-bis(3-methoxysalicylidene)-(R)-2,2-diamine-1,1'-binaphthyl)Nd(DMF)2(NO3)3]
  参考文献：
  名称：

  Construction and NIR luminescent property of hetero-bimetallic Zn–Nd complexes from two chiral salen-type Schiff-base ligands

  摘要：

  Two new near-infrared (NIR) luminescent Zn-Nd complexes [(ZnLNd)-Nd-1(OAc)(NO3)(2)] (3) and [(ZnLNd)-Nd-2(DMF)(2)(NO3)(3)] (4) have been obtained with two salen-type Schiff-base ligands H2L1 and H2L2, (H2L1=N,N'-bis(3-methoxysalicylidene)-(1s, 2s)-(-)1,2-dipheneylethylenediamine and H2L2=N,N'-bis(3-methoxysalicylidene)-(s)-2,2-diamine-1,1'-binaphthyl) from the reaction of different chiral diamines with o-vanillin. The X-ray crystal structure analysis reveals that both of them crystallize in the chiral space groups with P2(1), a = 10.1669(6), b = 19.3775(11), c = 17.4639(10) angstrom, beta = 94.8710(10)degrees, V = 3428.1(3) angstrom(3), Z = 4 for 3, and C2, a = 22.1914(13), b = 9.7886(6), c = 22.0138(13) angstrom, beta = 118.9590 (10)degrees, V=4372.5(4)angstrom(3), Z = 4 for 4. Complexes 3-4 are both dinuclear Zn-Nd structures, while suitable choice of chiral Schiff-base ligands could induce the different complexions of ligands and metal ions, and the functional control of ligand character shows a potentially effective way to the fine-tuning properties of NIR luminescence from Nd ions. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.04.056
• 作为产物：
  描述：

  N,N'-bis(3-methoxysalicylidene)(binaphthyl)-1,4-diamine 、 zinc diacetate 以 乙醇 为溶剂， 以71%的产率得到[Zn(N,N'-bis(3-methoxysalicylidene)-(R)-2,2-diamine-1,1'-binaphthyl)(H2O)]
  参考文献：
  名称：

  Construction and NIR luminescent property of hetero-bimetallic Zn–Nd complexes from two chiral salen-type Schiff-base ligands

  摘要：

  Two new near-infrared (NIR) luminescent Zn-Nd complexes [(ZnLNd)-Nd-1(OAc)(NO3)(2)] (3) and [(ZnLNd)-Nd-2(DMF)(2)(NO3)(3)] (4) have been obtained with two salen-type Schiff-base ligands H2L1 and H2L2, (H2L1=N,N'-bis(3-methoxysalicylidene)-(1s, 2s)-(-)1,2-dipheneylethylenediamine and H2L2=N,N'-bis(3-methoxysalicylidene)-(s)-2,2-diamine-1,1'-binaphthyl) from the reaction of different chiral diamines with o-vanillin. The X-ray crystal structure analysis reveals that both of them crystallize in the chiral space groups with P2(1), a = 10.1669(6), b = 19.3775(11), c = 17.4639(10) angstrom, beta = 94.8710(10)degrees, V = 3428.1(3) angstrom(3), Z = 4 for 3, and C2, a = 22.1914(13), b = 9.7886(6), c = 22.0138(13) angstrom, beta = 118.9590 (10)degrees, V=4372.5(4)angstrom(3), Z = 4 for 4. Complexes 3-4 are both dinuclear Zn-Nd structures, while suitable choice of chiral Schiff-base ligands could induce the different complexions of ligands and metal ions, and the functional control of ligand character shows a potentially effective way to the fine-tuning properties of NIR luminescence from Nd ions. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.04.056