Thiocarbonic acid S-cyanomethyl ester O-dodecyl ester | 31407-84-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: Thiocarbonic acid S-cyanomethyl ester O-dodecyl ester
• 英文别名: Dodecyl cyanomethylsulfanylformate
• CAS: 31407-84-8
• 化学式: C₁₅H₂₇NO₂S
• 分子量: 285.451
• InChiKey: ODHOSKPSKPAOMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  75.4
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• POLYMERIZABLE MONOMER, POLYMER COMPOUND FOR CONDUCTIVE POLYMER, AND METHOD FOR PRODUCING THE POLYMER COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20200247926A1

  公开（公告）日：2020-08-06

  Polymerization reaction is performed using a polymerizable monomer shown by the following general formula (1) and at least one monomer selected from monomers each having a structure of a salt among a lithium salt, a sodium salt, a potassium salt, and a nitrogen compound salt of a fluorosulfonic acid or the like; then, the structure of the salt of the repeating unit of a polymer obtained by the polymerization reaction is changed to the fluorosulfonic acid or the like by ion exchange. Thus, the present invention provides a polymer compound for a conductive polymer and a method for producing the polymer compound which is suitably used as a dopant for a fuel cell and a conductive material, and which is a copolymer containing a repeating unit of styrene having a 3,3,3-trifluoro-2-hydroxy-2-trifluoromethylisobutyl ether group, and a repeating unit having any of a fluorosulfonic acid, a fluorosulfonimide group, and a n-carbonyl-fluoro-sulfonamide group.

  聚合反应使用以下一般式（1）所示的可聚合单体和至少一种选择自锂盐、钠盐、钾盐和氟磺酸盐等盐结构的单体中的单体进行；然后，通过离子交换将聚合反应得到的聚合物的重复单元的盐结构改变为氟磺酸盐或类似物。因此，本发明提供了一种用作导电聚合物的聚合物化合物以及用作燃料电池和导电材料的掺杂剂的聚合物化合物的生产方法，该聚合物是含有3,3,3-三氟-2-羟基-2-三氟甲基异丁基醚基的苯乙烯重复单元和具有氟磺酸、氟磺酰亚胺基团和n-羰基-氟磺酰胺基团中的任何一种的重复单元的共聚物。
• Conductive polymer composite and substrate
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10559397B2

  公开（公告）日：2020-02-11

  An object of the present invention is to provide a conductive polymer composite which has good filterability and good film forming property by spin coating and, when a film is formed, can form a conductive film having high transparency and good flatness property. It is provided a conductive polymer composite comprising (A) a π-conjugated polymer, and (B) a dopant polymer containing a repeating unit “a” represented by the following general formula (1), and having a weight average molecular weight in the range of 1,000 to 500,000: wherein, R1, Z1, Rf1, and “a” are as defined in the specification.

  本发明的目的是提供一种导电聚合物复合材料，它通过旋涂具有良好的过滤性和成膜性，并且在成膜后可以形成具有高透明度和良好平整性的导电薄膜。本发明提供了一种导电聚合物复合材料，它包含 (A) π 共轭聚合物和 (B) 掺杂聚合物，掺杂聚合物含有由以下通式 (1) 表示的重复单元 "a"，其重量平均分子量在 1,000 至 500,000 之间： 其中，R1、Z1、Rf1 和 "a "如说明书中所定义。
• Polymer compound for conductive polymer and method for producing same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10851188B2

  公开（公告）日：2020-12-01

  A polymer compound for a conductive polymer contains one or more kinds of repeating units “a” represented by the following general formula (1) and has a weight average molecular weight in the range of 1,000 to 500,000, R1 represents a hydrogen atom or a methyl group; Rf1 represents a linear or branched alkyl group having 1 to 4 carbon atoms or a phenyl group, and has at least one fluorine atom or a trifluoromethyl group in Rf1; Z1 represents a single bond, an arylene group having 6 to 12 carbon atoms or —C(═O)—O—R2—; R2 represents a linear, branched or cyclic alkylene group having 1 to 12 carbon atoms, an arylene group having 6 to 10 carbon atoms or an alkenylene group having 2 to 10 carbon atoms, and may have an ether group, a carbonyl group or an ester group in R2; and “a” is 0

  一种用于导电聚合物的高分子化合物含有一种或多种由以下通式（1）表示的重复单元 "a"，其重量平均分子量在 1 000 至 500 000 之间、 R1 代表氢原子或甲基；Rf1 代表具有 1 至 4 个碳原子的直链或支链烷基或苯基，且在 Rf1 中至少有一个氟原子或三氟甲基；Z1 代表单键、具有 6 至 12 个碳原子的芳基或-C(═O)-O-R2-；R2 代表具有 1 至 12 个碳原子的直链、支链或环状亚烷基、具有 6 至 10 个碳原子的芳烯基或具有 2 至 10 个碳原子的烯基，R2 中可能具有醚基、羰基或酯基；"a "为 0
• CONDUCTIVE POLYMER COMPOSITE AND CONDUCTIVE POLYMER COMPOSITION
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3693979B1

  公开（公告）日：2022-05-04
• POLYMER COMPOUND FOR A CONDUCTIVE POLYMER AND METHOD FOR MANUFACTURING SAME
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20150175722A1

  公开（公告）日：2015-06-25

  A polymer compound for a conductive polymer including one or more repeating units represented by general formula (1), which has been synthesized by ion-exchange of a lithium salt, sodium salt, potassium salt, or nitrogen compound salt of a sulfonic acid residue, and has a weight average molecular weight in the range of 1,000 to 500,000, wherein R 1 represents a hydrogen atom or methyl group, R 2 represents a single bond, an ester group, or a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms which may have either or both of an ether group and an ester group, and Z represents a phenylene group, naphthylene group, or ester group. There can be provided a polymer compound for a conductive polymer having a specific super strongly acidic sulfo group, which is soluble in an organic solvent, and suitably used for a fuel cell or dopant for a conductive material.