rubidium titanyl phosphate | 12690-26-5

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 非金属氧阴离子化合物
• 英文名称: rubidium titanyl phosphate
• CAS: 12690-26-5
• 化学式: OTi*O₄P*Rb
• 分子量: 244.319
• InChiKey: AEVWYUMMJSGGEN-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  rubidium 、 hydrated titanyl phosphate 以 水 为溶剂， 生成 rubidium titanyl phosphate
  参考文献：
  名称：

  Thermodynamics of cationic substitutions on titanyl hydrogen phosphate

  摘要：

  Heterophasic substitution of Group I and Group II metal cations for hydrogen ions of titanyl hydrogen phosphate in aqueous solutions has been studied by a potentiometric method. The thermodynamic parameters of the process have been determined. The exchange constants depend on the degree of cation hydration and increase in the following orders: Li+ < Na+ < K+ < Rb+ < Cs+ and Mg2+ < Ca2+ < Sr2+ < Ba2+. Our results make it possible to determine conditions for the efficient deactivation of high-salt liquid radioactive wastes and for the synthesis of stoichiometric compounds of the KTP family.

  DOI：

  10.1134/s0036023608040037

文献信息

• Composition-dependent dielectric properties of RbTiOPO4 single crystals
  作者：Jna. Gavaldà、J. J. Carvajal、X. Mateos、M. Aguiló、F. Díaz

  DOI：10.1063/1.3258000

  日期：2009.11.2

  We measured the ionic conductivity for two single crystals of RbTiOPO4 grown in self-fluxes with different chemical composition. Ionic conductivity depended on the composition of the self-flux solution in which the crystal was grown. One of the samples showed an anisotropic behavior along the three crystallographic axes while the other showed a nearly isotropic behavior of the ac conductivity.

  我们测量了在具有不同化学成分的自助熔剂中生长的两个 RbTiOPO4 单晶的离子电导率。离子电导率取决于生长晶体的自熔溶液的组成。其中一个样品显示出沿三个晶轴的各向异性行为，而另一个样品显示出几乎各向同性的交流电导率行为。
• ——
  作者：E. P. Lokshin、V. I. Ivanenko、I. A. Udalova、V. T. Kalinnikov

  DOI：10.1023/a:1026169822490

  日期：——
• Ferroelectric Phase Transitions and Properties of Crystals of the KTiOPO4 Family
  作者：V. K. Yanovskii、V. I. Voronkova

  DOI：10.1002/pssa.2210930232

  日期：1986.2.16
• Kaduk, J. A.; Jarman, R. H., Zeitschrift für Kristallographie
  作者：Kaduk, J. A.、Jarman, R. H.

  DOI：——

  日期：——