糠酚树脂 | 26338-61-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 糠酚树脂
• 英文名称: Furan-2-carbaldehyde;phenol
• CAS: 26338-61-4
• 化学式: C11H10O3
• 分子量: 190.19
• InChiKey: ANAGEECPKFGKEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.48
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  苯酚 、 糠醛 、 disodium;carbonate 反应 3.69h， 生成 糠酚树脂
  参考文献：
  名称：

  Process for producing a molded product and the molded product produced

  摘要：

  该过程和从中得出的产品使用可塑性组合物，该组合物是由粉末或其他可混合形式的20-80%重量的酚醛-呋喃醛Novolac树脂和20-80%重量的酚醛树脂混合物形成的，这些混合物分散在水中，可以是溶液或悬浮液，所述百分比基于Novolac和resol树脂的总重量，并且所述Novolac树脂中的醛至少包含50摩尔百分比，优选实质上为100％的呋喃醛。该组合物有利地含有胺，例如六亚甲基四胺（“六亚”），其量相当于总酚类组分的1-15％，优选为2-10％的六亚甲基四胺。该组合物是通过在脲醛树脂脱水之前将预先形成的酚醛-呋喃醛Novolac添加到脲醛树脂中而制成的，以产生改性聚合物化产物。该组合物特别适用于与含碳填料混合使用，优选为石墨，其比例可高达总组合物的76％重量。通常，在这种混合物中，石墨可以包含30-76％，有利地为35-65％，优选为40-60％的成型组合物。该玻璃状碳在电学特性和适当成型、碳化和石墨化成大型形状，特别是比以往生产的薄板更为无应力和无裂纹或孔隙方面得到改善。

  公开号：

  US04626569A1

文献信息

• Vitreous carbon
  申请人：Plastics Engineering Company

  公开号：US04668496A1

  公开（公告）日：1987-05-26

  The vitreous carbon disclosed herein is prepared from the molded product of a moldable composition produced from co-reacted mixtrues of powder or otherwise blendable form of 20-80% by weight of a phenolic-furfuraldehyde Novolac resin and of 20-80% by weight of a phenolic-aldehyde resol resin dispersed in water, either in solution or suspension, the percentages being based on the combined weight of the Novolac and resol resins, and the aldehyde in said Novolac resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde. The composition advantageously contains an amine such as hexamethylenetetramine ("hexa") in an amount equivalent to 1-15%, preferably 2-10% of hexamethylenetetramine based on the total amount of phenolic component. The composition is made by adding the preformed phenol-furfuraldehyde Novolac to the resol resin prior to dehydration of the resol resin to produce a grafted polymerization product of improved properties. This composition is particularly useful in admixture with a carbonaceous filler, preferably graphite in a proportion as high as 76% by weight based on the total composition. Generally in such admixtures the graphite may comprise 30-76%, advantageously 35-65% and preferably 40-60% of the molding composition. The vitreous carbon is improved in electrical properties and in the capability of being suitably molded, carbonized and graphitized into large shapes, particularly thin plates which are much more stress-free and crack or pore-free than otherwise produced.

  此处所披露的玻璃炭是由可塑性混合物的成型产品制备而成的，该混合物由20-80重量％的酚-呋喃醛诺伍酚树脂和20-80重量％的酚-醛树脂在水中分散而成，其中酚醛树脂的醛含量至少包括50摩尔％，优选为实质上100％的呋喃醛，所述百分比基于诺伍酚和酚醛树脂的总重量。该混合物有利地含有胺，例如六亚甲基四胺（“六亚”），其量相当于1-15％，优选为2-10％的六亚基于酚组分的总量。在脲酸树脂脱水之前，将预形成的酚-呋喃醛诺伍酚添加到酚醛树脂中，以产生改性聚合物的产品，其性能得到改善。该混合物特别适用于与碳质填料混合，优选为石墨，比例高达76重量％，基于总成分。通常在这样的混合物中，石墨可以占30-76％，有利地占35-65％，优选为40-60％的成型混合物。玻璃炭在电学性能和适当成型，碳化和石墨化成大型形状方面得到改善，特别是薄板，这些薄板比其他生产的薄板更无应力，无裂纹或无孔。
• Thermosettable compositions convertible to vitreous carbon and process
  申请人：Plastics Engineering Company

  公开号：US04526924A1

  公开（公告）日：1985-07-02

  The compositions disclosed herein are suitable for thermosetting and conversion to vitreous carbon. They comprise intimate uniform mixtures of powder or otherwise blendable form of 20-80% by weight of a solid phenolic-aldehyde Novolak resin and of 20-80% by weight of a solid phenolic-aldehyde resol resin, the percentages being based on the combined weight of the Novolak and resol resins, and the aldehyde in said Novolak resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde, together with a carbonaceous filler, preferably graphite, in a proportion as high as 76% by weight based on the total composition. Generally the graphite may comprise 30-70%, advantageously 35-65% and preferably 40-60% of the molding composition. The vitreous carbon produced from these compositions have improved properties in electrical properties and in the capability of being suitably molded and carburized into large thin plates which are much more stress-free than otherwise produced. The composition may also contain 0-12 parts, preferably 0.12-8 parts hexamethylenetetramine per 100 parts of Novolak resin. The intimate mixture of these resins is advantageously made by blending resin components having a particle size of less than 40 mesh, preferably less than 100 mesh.

  本文所披露的组合物适用于热固化和转化为玻璃炭。它们由20-80%重量的固态酚醛Novolak树脂和20-80%重量的固态酚醛Resol树脂的粉末或可混合形式的均匀混合物组成，所述百分比基于Novolak和Resol树脂的总重量，且Novolak树脂中的醛至少包含50摩尔百分比，优选实质上为100％的呋喃醛，以及一种碳质填料，优选石墨，其比例高达总组合物的76％重量。通常，石墨可以占成型组合物的30-70％，有利地为35-65％，优选为40-60％。由这些组合物产生的玻璃炭在电学性能和适当成型和炭化成大型薄板的能力方面具有改善的性能，这些薄板比其他方式生产的薄板具有更少的应力。该组合物还可以含有0-12份，优选为每100份Novolak树脂0.12-8份的六亚甲基四胺。这些树脂的均匀混合物优选地是通过混合粒径小于40目，优选小于100目的树脂组分制成的。
• Phenolic polymer nanotube and producing the same
  申请人：Kijima Tsuyoshi

  公开号：US20060160981A1

  公开（公告）日：2006-07-20

  A phenolic polymer nanotube having a specific shape is obtained by carrying out: a reaction step in which at least one monomer selected from a group of phenol and derivative thereof is reacted with at least one aldehyde monomer in the presence of basic condensing agent; a treatment step in which a precursor obtained in the reaction step is treated with a strong base; and a polymerization step in which a reacted precursor obtained in the treatment step is dropped into aqueous solution, containing the monomer and a surfactant, so as to polymerize the reacted precursor.

  通过进行以下步骤，可以获得具有特定形状的酚聚合物纳米管：在碱性缩合剂的存在下，至少选择酚及其衍生物之一的单体与至少一种醛单体进行反应步骤；在反应步骤中获得的前体物质经过强碱处理步骤；将在处理步骤中获得的反应前体滴入含有单体和表面活性剂的水溶液中，以使反应前体聚合的聚合步骤。
• Vitreous carbon and process for preparation thereof
  申请人：Plastics Engineering Company

  公开号：US04550015A1

  公开（公告）日：1985-10-29

  The vitreous carbon disclosed herein is prepared from intimate uniform mixtures of powder or otherwise blendable form of 20-80% by weight of a solid phenolic-aldehyde Novolak resin and of 20-80% by weight of a solid phenolic-aldehyde resol resin, the percentages being based on the combined weight of the Novolak and resol resins, and the aldehyde in said Novolak resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde, together with a carbonaceous filler, preferably graphite, in a proportion as high as 76% by weight based on the total composition. Generally the graphite may comprise 30-70%, advantageously 35-65% and preferably 40-60% of the molding composition. The vitreous carbon is improved in electrical properties and in the capability of being shaped into large thin plates which are much more stress-free than otherwise produced. The intimate mixture of the resins used for this preparation is advantageously made by blending resin components having a particle size of less than 40 mesh, preferably less than 100 mesh.

  本文所披露的玻璃炭是由20-80%重量的固态酚醛Novolak树脂和20-80%重量的固态酚醛Resol树脂的粉末或可混合形式的密切均匀混合物制备而成，所述百分比基于Novolak和Resol树脂的组合重量，且Novolak树脂中的醛至少包含50摩尔百分比，优选基本上为100％的呋喃醛，以及一种碳质填料，优选为石墨，其比例可高达总成分的76％重量。通常，石墨可以占成型组合物的30-70％，有利的是35-65％，优选为40-60％。该玻璃炭在电学性能和成型成大型薄板的能力方面得到改善，这些薄板比其他生产的薄板更无应力。用于此制备的树脂的密切混合物通常是通过混合粒径小于40目，优选小于100目的树脂组分制成的。
• Liquid crystal sealing agent and liquid crystalline display cell using the same
  申请人：Imaizumi Masahiro

  公开号：US20060208219A1

  公开（公告）日：2006-09-21

  The present invention relates to a sealant for liquid crystals having extremely low contamination nature to a liquid crystal, excellent coatability and bondability to a substrate, long service life and pot life and high adhesive strength. A sealant for liquid crystals of the present invention is characterized by comprising (a) an epoxy resin represented by general formula (1): (wherein a represents an integer of 2 to 4; n represents 0 to 3 (average value); R represents a divalent hydrocarbon group of 2 to 6 carbon atoms; A represents a polyvalent aromatic group; and G represents a glycidyl group, provided that when n is 0, (a) an epoxy resin represented by general formula (1) is a bisphenol S-type.), (b) a thermo-curing agent, (c) and a filler having average particle diameter of not larger than 3 μm.

  本发明涉及一种密封剂，用于液晶，具有极低的对液晶的污染性，对基底具有优异的涂覆性和粘结性，具有长久的使用寿命和潜伏期，以及高粘接强度。本发明的液晶密封剂的特点在于包括(a)由通式(1)表示的环氧树脂：(其中a表示2到4的整数；n表示0到3（平均值）；R表示2到6个碳原子的二价碳氢基团；A表示多价芳香基团；G表示环氧基团，但当n为0时，(a)由通式(1)表示的环氧树脂为双酚S型)；(b)热固化剂；(c)和平均粒径不大于3μm的填料。