[N,N'-ethylenebis(acetylacetoniminato)]cobalt(II) hydrate | 36802-26-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [N,N'-ethylenebis(acetylacetoniminato)]cobalt(II) hydrate
• CAS: 36802-26-3
• 化学式: C₁₂H₁₈CoN₂O₂*H₂O
• 分子量: 299.296
• InChiKey: MGTGZZUAHUDTDP-XWKGGOARSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [N,N'-ethylenebis(acetylacetoniminato)]cobalt(II) hydrate 在 吡啶 、 sodium azide 、 双氧水 作用下， 以 水 、 丙酮 为溶剂， 生成 (pyridine)azido[N,N'-ethylenebis(acetylacetoniminato)]cobalt(III)
  参考文献：
  名称：

  Lindoy, Leonard F.; Louie, Hon Way, Inorganic Chemistry, 1981, vol. 20, # 12, p. 4186 - 4193

  摘要：

  DOI：
• 作为产物：
  描述：

  cobalt(II) diacetate tetrahydrate 、 N,N'-ethylenebis(4-iminopentan-2-one) 以 乙醇 为溶剂， 以54%的产率得到[N,N'-ethylenebis(acetylacetoniminato)]cobalt(II) hydrate
  参考文献：
  名称：

  Synthesis and Physicochemical Properties of Some β‐Ketoaminato Cobalt(II) Chelates and Their Adducts with 2,2′‐Bipyridine and 1,10‐Phenanthroline

  摘要：

  The cobalt(II) beta-ketoamines complexes {Co[CH3C(O)CHC(CH3)NR](2); R = CH3, CH2(OH)CH2, C4H9} and ketoiminates {Co[CH3C(O)CH(CH3) C(-N(CH2)(n)N-)C(CH3)CHC(O)CH3]} and their adducts with 2,2'-bipyridine (bipy) and 1,10-phenanthroline (phen) have been synthesized and characterized by elemental analyses, magnetic susceptibility, conductivity, infrared, and electronic spectral measurements. The ligands coordinate to the cobalt ion in a bidentate manner using the N2O2 chromophore. The effective magnetic moments (mu(eff)) observed for the complexes are in the range of 4.20-5.30 BM. Electronic spectra results and magnetic susceptibility measurements are consistent with the adoption of a four-coordinate geometry for the cobalt(II) chelates and a six-coordinate octahedral geometry for the 2,2'-bipyridine and 1,10-phenanthroline adducts. The available conductance data in nitromethane indicates that the compounds are non-electrolytes.

  DOI：

  10.1081/sim-200026294