6-(benzyloxy)-2-naphthalene carbonyl chloride | 122179-30-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-(benzyloxy)-2-naphthalene carbonyl chloride
• 英文别名: 2-benzyloxynaphthalene-6-carboxylic acid chloride；6-benzyloxy-2-naphthoic acid chloride；6-benzyloxynaphthalene-2-carboxylic acid chloride；6-(Benzyloxy)naphthalene-2-carbonyl chloride；6-phenylmethoxynaphthalene-2-carbonyl chloride
• CAS: 122179-30-0
• 化学式: C₁₈H₁₃ClO₂
• 分子量: 296.753
• InChiKey: NHZQLBHSBDMUGE-UHFFFAOYSA-N

物化性质

• 沸点：
  453.8±20.0 °C(Predicted)
• 密度：
  1.264±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-(benzyloxy)-2-naphthalene carbonyl chloride 在 palladium on activated charcoal sodium hydroxide 、 sodium azide 、 氢气 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 生成 N-(6-hydroxy-[2]naphthyl)-acetamide
  参考文献：
  名称：

  Synthesis of a AT base pair model in DNA and determination of hydrogen bonding strength on the formation of base triplet T:AT in CDCl3

  摘要：

  A molecular model has been synthesized to determine the hydrogen-bonding strength between AT and T in the base triplet, T:AT. A strong preference (>95%) of Watson-Crick mode along with 91% hydrogen-bonded conformation is observed in the model compound. The association constants of the AT model with 1-propyluracil and glutarimide are 15 M-1 and 5.2 M-1, respectively, in CDCl3 at 296 +/- 0.5 K. Negative cooperativity by pre-existing hydrogen bonds might be involved in the intermolecular binding events. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)10257-x
• 作为产物：
  描述：

  2-苄氧基-6-溴萘 在 正丁基锂 、 氯化亚砜 作用下， 生成 6-(benzyloxy)-2-naphthalene carbonyl chloride
  参考文献：
  名称：

  Synthesis of a AT base pair model in DNA and determination of hydrogen bonding strength on the formation of base triplet T:AT in CDCl3

  摘要：

  A molecular model has been synthesized to determine the hydrogen-bonding strength between AT and T in the base triplet, T:AT. A strong preference (>95%) of Watson-Crick mode along with 91% hydrogen-bonded conformation is observed in the model compound. The association constants of the AT model with 1-propyluracil and glutarimide are 15 M-1 and 5.2 M-1, respectively, in CDCl3 at 296 +/- 0.5 K. Negative cooperativity by pre-existing hydrogen bonds might be involved in the intermolecular binding events. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)10257-x

文献信息

• Liquid crystal compound
  申请人：Showa Shell Sekiyu Kabushiki Kaisha

  公开号：US05891359A1

  公开（公告）日：1999-04-06

  The novel liquid crystal compounds of the present invention are represented by the following formulas \x9bI!-\x9bII! and have tristable molecular orientation states and can be used for display devices and electrooptical devices. ##STR1## wherein R.sub.1 represents an alkyl group of 5-18 carbon atoms; R.sub.2 represents an alkyl group of 6-16 carbon atoms; R.sub.3 represents an alkyl group of 8-18 carbon atoms; R.sub.4 represents an alkyl group of 6-14 carbon atoms; Y represents ##STR2## and * indicates an optically active center.

  本发明的新型液晶化合物由以下公式\x9bI!-\x9bII!表示，具有三态分子取向状态，可用于显示器件和电光器件。其中，R.sub.1代表5-18个碳原子的烷基基团；R.sub.2代表6-16个碳原子的烷基基团；R.sub.3代表8-18个碳原子的烷基基团；R.sub.4代表6-14个碳原子的烷基基团；Y代表##STR2##，*表示一个光学活性中心。
• Liquid crystal compounds
  申请人：Showa Shell Sekiyu Kabushiki Kaisha

  公开号：US05310500A1

  公开（公告）日：1994-05-10

  Antiferroelectric liquid crystal compounds are provided which have the formula ##STR1## wherein R.sub.1 represents an alkyl group having 5-18 carbon atoms, R.sub.2 represents an alkyl group having 6-16 carbon atoms, Y represents a group ##STR2## and A represents a group ##STR3##

  反铁电液晶化合物具有以下公式：其中R1代表一个含有5-18个碳原子的烷基团，R2代表一个含有6-16个碳原子的烷基团，Y代表一个基团，A代表一个基团。
• Liquid crystal compounds and compositions
  申请人：SANYO CHEMICAL INDUSTRIES LTD.

  公开号：EP0518636A1

  公开（公告）日：1992-12-16

  Liquid crystal naphthalene compounds, represented by the following formula (1) are disclosed.         R-Z-A-#-NAP-Z′-R′   (1) In the formula (1), R is an alkyl group containing 1 to 18 carbon atoms; R′ is an alkyl group containing 1 to 21 carbon atoms; NAP represents 2,6-naphthylene group;# represents C≡C; A, Z and Z′ are as follows: 1) A is Pyr> and (a) Z is - and Z′ is O or COO or (b) Z is OCO and Z′ is - or O; 2) A is FPhF and (a) Z is - or O and Z′ is -, O or COO or (b) Z is OCO and Z′ is - or O; 3) A is FPh and (a) Z is - and Z′ is O or COO, (b) Z is O and Z′ is -, O or COO or (c) Z is OCO and Z′ is - or O; 4) A is

  揭示了液晶萘化合物，其表示为以下公式（1）：R-Z-A-#-NAP-Z′-R′   （1） 在公式（1）中，R是含有1至18个碳原子的烷基基团；R′是含有1至21个碳原子的烷基基团；NAP代表2,6-萘基团；#代表C≡C；A，Z和Z′如下： 1）A是Pyr>，并且（a）Z是-，Z′是O或COO，或者（b）Z是OCO，Z′是-或O； 2）A是FPhF，并且（a）Z是-或O，Z′是-，O或COO，或者（b）Z是OCO，Z′是-或O； 3）A是FPh，并且（a）Z是-，Z′是O或COO，或者（b）Z是O，Z′是-，O或COO，或者（c）Z是OCO，Z′是-或O； 4）A是
• 2,2'-Binaphthalene Ester Chiral Dopants for Cholesteric Liquid Crystal Displays
  申请人：Diehl Donald R.

  公开号：US20140054498A1

  公开（公告）日：2014-02-27

  A liquid crystal composition comprising a chiral dopant compound represented by the following structure (Structure 1): wherein: R1 and R2 are independently hydrogen, —(C═O)R9, —(C═O)R10, alkyl, aryl, alkaryl, alkenyl, cycloalkyl, alkoxyaryl, or heterocyclic all either substituted or unsubstituted, or combine to form a carbocyclic or heterocyclic ring; and R3-R9 are as described in the disclosure. Also featured are liquid crystal compositions comprising a chiral dopant compound represented by any of Structure 2-4 as described in the disclosure.

  一种液晶组合物，包括由以下结构（结构1）表示的手性掺杂剂化合物：其中：R1和R2独立地是氢，—(C═O)R9，—(C═O)R10，烷基，芳基，烷芳基，烯基，环烷基，烷氧基芳基，或杂环烷基，均为取代或未取代，或结合形成碳环或杂环；R3-R9如披露中所述。还包括由披露中描述的结构2-4中的任何一个表示的手性掺杂剂化合物的液晶组合物。
• Tetraoxybiphenyl Ester Chiral Dopants for Cholesteric Liquid Crystal Displays
  申请人：Diehl Donald R.

  公开号：US20120273725A1

  公开（公告）日：2012-11-01

  A liquid crystal composition comprising a chiral dopant compound represented by the following formula: wherein: R1, R2 are independently aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl, alkaryl or heterocyclic all either substituted or unsubstituted, or combine to form a carbocyclic or heterocyclic ring; R3 and R4 are independently hydrogen, halogen, cyano, alkoxy, NHCOR7, NHSO2R7, COOR7, OCOR7, aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl, alkaryl or heterocyclic all either substituted or unsubstituted, or combine with either R1 or R2 to form a carbocylic or heterocyclic ring; R5 and R6 are independently hydrogen, CH2, CH, alkyl or aryl either substituted or unsubstituted, COOR7, or combine with L to form a carbocyclic or heterocyclic ring; R7 is aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl or heterocyclic all either substituted or unsubstituted; L is the non-metallic elements required to form a carbocyclic or heterocyclic ring, or a single bond or a double bond; m is 1-3; n is 0-12.

  一种液晶组合物，包括由以下式表示的手性掺杂剂化合物： 其中：R1，R2独立地为芳基，烷基，烯基，环烷基，烷氧基芳基，烷基芳基或杂环基，均为取代或未取代，或结合形成碳环或杂环；R3和R4独立地为氢，卤素，氰基，烷氧基，NHCOR7，NHSO2R7，COOR7，OCOR7，芳基，烷基，烯基，环烷基，烷氧基芳基，烷基芳基或杂环基，均为取代或未取代，或与R1或R2之一结合形成碳环或杂环；R5和R6独立地为氢，CH2，CH，烷基或芳基，均为取代或未取代，COOR7，或与L结合形成碳环或杂环；R7为芳基，烷基，烯基，环烷基，烷氧基芳基或杂环基，均为取代或未取代；L为形成碳环或杂环所需的非金属元素，或单键或双键；m为1-3；n为0-12。