Photoredox decomposition of tin(II), lead(II), antimony(III) and bismuth(III) iodide complexes in solution
作者:Karin Oldenburg、Arnd Vogler、Ildikó Mikó、Ottó Horváth
DOI:10.1016/0020-1693(95)04980-0
日期:1996.7
The main group metal complexes SnI3−, PbI3−, SbI4− and BiI4− display long-wavelength absorption bands which are assigned to sp/LMCT transitions. The photochemistry of these complexes is determined by the CT character of their lowest-energy excited state. The photolysis in acetonitrile leads to a photoredox decomposition which yields I3− and the elemental metals as final products. The results of the