[n-Bu4N][(O-i-Pr)3Ti(μ-O-i-Pr)Ti(O-i-Pr)3] | 300344-01-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [n-Bu4N][(O-i-Pr)3Ti(μ-O-i-Pr)Ti(O-i-Pr)3]
• 英文别名: fluorotitanium(3+);propan-2-olate;tetrabutylazanium;titanium(4+);fluoride
• CAS: 300344-01-8
• 化学式: C₁₆H₃₆N*C₂₁H₄₉F₂O₇Ti₂
• 分子量: 789.841
• InChiKey: NRHQXEQVSYMKTJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  titanium(IV) isopropylate 、 tetrabutylazanium,fluoride,hydrofluoride 以 正己烷 、 二氯甲烷 为溶剂， 以85.4%的产率得到[n-Bu4N][(O-i-Pr)3Ti(μ-O-i-Pr)Ti(O-i-Pr)3]
  参考文献：
  名称：

  Application of n-Bu₄NHF₂ as a Fluorinating Agent for the Preparation of Fluoroanions:  Synthesis and Crystal Structure of the Anions [t-BuPO₃AlF₂]₂^2-, [PhPO₃AlF₂]₂^2-, and [(O-i-Pr)₃Ti(μ-F)₂(μ-O-i-Pr)Ti(O-i-Pr)₃]^-

  摘要：

  The first phosphonate anions of aluminum-containing fluorine and an anionic bridged fluoroalkoxy derivative of titanium have been realized using n-Bu4NHF2 as a fluorinating agent in organometallic synthesis. Reactions of [RPO3AlMe](4) [R = Ph (1), t-Bu] with n-Bu4NHF2 yield organic-soluble compounds of the type [n-Bu4N](2)[RPO3AlF2](2) [R = Ph (2), t-Bu (3)], whereas the reaction of Ti(O-i-Pr)(4) with n-Bu4NHF2 results in the formation of [n-Bu4N][(O-i-Pr)(3)Ti(mu-F)(2)(mu-O-i-Pr)Ti(O-i-Pr)(3)] (4). These compounds have been obtained in high yields and have been adequately characterized through spectroscopic techniques and X-ray diffraction studies.

  DOI：

  10.1021/ic991453b