[Cu(ethylene diamine)(N(CN)2)2](n) | 620158-26-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu(ethylene diamine)(N(CN)2)2](n)
• CAS: 620158-26-1
• 化学式: C₆H₈CuN₈
• 分子量: 255.729
• InChiKey: DGVRLKVZSCKPAK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 sodium dicyanamide 、 乙二胺 以 甲醇 为溶剂， 以71%的产率得到[Cu(ethylene diamine)(N(CN)2)2](n)
  参考文献：
  名称：

  [Cu(dca)2(en)]n: a two-dimensional copper(II) coordination polymer with both μ1,5-dca and pseudo-μ1,3-dca bridges

  摘要：

  A copper(II)-dicyanamide (dca = dicyanamide anion, [N(CN)(2)](-)) compound, [Cu(dca)2(en)](n) (1) (en = ethylene diamine), has been synthesized and its structure has been determined by single X-ray diffraction analysis. It crystallizes in the monoclinic space group C2/c with unit cell dimensions: a = 12.031(2) Angstrom, b = 8.614(1) Angstrom, c = 19.528(3) Angstrom, beta = 99.499degrees, Z = 8, and V = 1996.0(4) Angstrom(3). 1 is the first coordination polymer containing both mu(1,5)-dca and pseudo-mu(1,3)-bridging dca. The adjacent copper atoms are connected by dca with mu(1,5)-bridging mode to form a chain structure. Furthermore, the chains are cross linked via the pseudo-mu(1,3)-bridging dca into a 2D layer structure. Magnetic characterization of 1 suggests that the complex exhibits a weak antiferromagnetic interaction between the copper(II) ions. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00463-0