(E)-1-iodo-4-(4-methoxystyryl)benzene | 57083-02-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (E)-1-iodo-4-(4-methoxystyryl)benzene
• 英文别名: 4-Iod-4'-methoxy-trans-stilben；(E)-1-(p-Methoxyphenyl)-2-(p-iodphenyl)-ethylen；(E)-4-iodostyrylmethoxybenzene；1-iodo-4-[(E)-2-(4-methoxyphenyl)ethenyl]benzene
• CAS: 57083-02-0
• 化学式: C₁₅H₁₃IO
• 分子量: 336.172
• InChiKey: NUIVTEFCSHTKQY-NSCUHMNNSA-N

物化性质

• 熔点：
  215-217 °C(Solv: chloroform (67-66-3); hexane (110-54-3))
• 沸点：
  407.7±24.0 °C(Predicted)
• 密度：
  1.537±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯乙烯 、 (E)-1-iodo-4-(4-methoxystyryl)benzene 在 苯基脲 、 palladium diacetate 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 22.0h， 以77%的产率得到1-methoxy-4-((E)-4-((E)-styryl)styryl)benzene
  参考文献：
  名称：

  A one-pot synthesis of unsymmetrical bis-styrylbenzenes

  摘要：

  An efficient and widely applicable one-pot synthesis of unsymmetrical (E,E)-bis-styrylbenzenes using successive Heck and Horner-Wadsworth-Emmons reactions is described. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.08.083
• 作为产物：
  描述：

  4-碘苄基溴 生成 (E)-1-iodo-4-(4-methoxystyryl)benzene
  参考文献：
  名称：

  用对-溴-和对-碘-亚苄基三苯并三苯基砷烷处理羰基化合物中的烷基化物仅形成烯烃的研究

  摘要：

  已经形成了两种新的半稳定的砷化氢，对-溴-和对-碘-亚苄基三苯苯基砷烷，并用一系列羰基化合物处理，仅生成反式烯烃。在任何情况下均未获得环氧化物。

  DOI：

  10.1016/s0022-328x(00)83551-2

文献信息

• MOLECULES HAVEING PESTICIDAL UTILIY AND INTERMEDIATES, COMPOSITIONS AND PROCESSES RELATED THERETO
  申请人：Dow AgroSciences LLC

  公开号：US20180098541A1

  公开（公告）日：2018-04-12

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

  这份披露涉及具有对节肢动物门、软体动物门和线虫门害虫有用的杀虫性的分子领域，用于生产这种分子的过程，用于这种过程的中间体，含有这种分子的杀虫组合物，以及使用这种杀虫组合物对这些害虫进行处理的过程。这些杀虫组合物可以用作螨虫剂、杀虫剂、螨虫剂、软体动物杀虫剂和线虫杀虫剂。本文件披露了具有以下式（“式一”）的分子。
• MOLECULES HAVING PESTICIDAL UTILITY, AND COMPOSITIONS, AND PROCESSES, RELATED THERETO
  申请人：Dow AgroSciences LLC

  公开号：EP3964495A1

  公开（公告）日：2022-03-09

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").

  本公开涉及对节肢动物门、软体动物门和线虫纲害虫具有杀虫作用的分子、生产此类分子的工艺、用于此类工艺的中间体、含有此类分子的杀虫组合物以及使用此类杀虫组合物对付此类害虫的工艺。这些杀虫组合物可用作杀螨剂、杀虫剂、杀螨剂、杀软体动物剂和杀线虫剂等。本文公开了具有下式（"式一"）的分子。
• Molecules having pesticidal utility and intermediates, compositions and processes related thereto
  申请人：Dow AgroSciences LLC

  公开号：US10258045B2

  公开（公告）日：2019-04-16

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

  本公开涉及对节肢动物门、软体动物门和线虫动物门害虫具有杀虫作用的分子、生产此类分子的工艺、用于此类工艺的中间体、含有此类分子的杀虫组合物以及使用此类杀虫组合物对付此类害虫的工艺。这些杀虫组合物可用作杀螨剂、杀虫剂、杀螨剂、杀软体动物剂和杀线虫剂等。本文公开了具有下式（"式一"）的分子。
• Molecules having pesticidal utility, and intermediates, compositions, and processes related thereto
  申请人：Dow AgroSciences LLC

  公开号：US10993440B2

  公开（公告）日：2021-05-04

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

  本公开涉及对节肢动物门、软体动物门和线虫动物门害虫具有杀虫作用的分子、生产此类分子的工艺、用于此类工艺的中间体、含有此类分子的杀虫组合物以及使用此类杀虫组合物对付此类害虫的工艺。这些杀虫组合物可用作杀螨剂、杀虫剂、杀螨剂、杀软体动物剂和杀线虫剂等。本文公开了具有下式（"式一"）的分子。
• Practical Synthesis of Vinyl-Substitutedp-Phenylenevinylene Oligomers and Their Triethoxysilyl Derivatives
  作者：Erli Sugiono、Thorsten Metzroth、Heiner Detert

  DOI：10.1002/1615-4169(20010430)343:4<351::aid-adsc351>3.0.co;2-2

  日期：2001.4.30

  Luminescent semiconducting organic compounds are widely used as active layers in electro-optical devices. Apart from conjugated polymers, monodisperse oligomers also represent attractive materials. The synthesis of stilbenoid oligomers with polymerizable end groups is presented. Oligo(phenylenevinylene)s with terminal vinyl groups 17-19 are prepared in good yields by Horner-Emmons olefinations or by the fleck reaction of the iodo-substituted oligomers 15, 16 with cornpressed ethene. Triethoxysilyl groups can be linked via rigid 1,2-vinylene units to the chromophores 26-30, either in the direct reaction of 14, 24 with silanes 21, 22 or by cross-metathesis of 17-19 with the vinyl silanes 21, 22 using Grubbs catalyst.