1-(tetraphenylstiboxy)-3-oxybenzene toluene adduct | 511270-36-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1-(tetraphenylstiboxy)-3-oxybenzene toluene adduct
• 英文别名: 3-(tetraphenyl-λ5-stibanyl)oxyphenol;toluene
• CAS: 511270-36-3
• 化学式: C₇H₈*C₃₀H₂₅O₂Sb
• 分子量: 631.418
• InChiKey: KYPKPAOYCQHJCV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.29
• 重原子数：
  40.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  29.46
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  pentaphenylantimony 、 甲苯 、 间苯二酚 以 甲苯 为溶剂， 以85%的产率得到1-(tetraphenylstiboxy)-3-oxybenzene toluene adduct
  参考文献：
  名称：

  摘要：

  The toluene solvate of 1-(tetraphenylstiboxy)-3-oxybenzene (1) was synthesized by reacting pentaphenylantimony with resorcin (at a molar ratio of 1 : 1) in toluene at 20degreesC, and the 1 : 3 complex (II) of 1,4-bis(tetraphenylstiboxy)benzene with hydroquinone was synthesized by reacting pentaphenylantimony with hydroquinone (at a molar ratio of 1 : 2) under similar conditions. The structures of the compounds obtained were determined using X-ray diffraction analysis. The Sb atoms in I and II have a distorted trigonal-bipyramidal coordination to the axial phenolate groups.

  DOI：

  10.1023/a:1021198513120