4-甲基-7-氧杂双环[4.1.0]庚烷-3-羧酸2-丙烯基酯 | 10138-39-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 中文名称: 4-甲基-7-氧杂双环[4.1.0]庚烷-3-羧酸2-丙烯基酯
• 英文名称: 4,5-epoxy-2-methyl-cyclohexanecarboxylic acid allyl ester
• 英文别名: 4,5-Epoxy-2-methyl-cyclohexancarbonsaeure-allylester；allyl 3,4-epoxy-6-methylcyclohexanecarboxylate；prop-2-enyl 4-methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylate
• CAS: 10138-39-3
• 化学式: C₁₁H₁₆O₃
• 分子量: 196.246
• InChiKey: SZOBRFMKKNAYTL-UHFFFAOYSA-N

物化性质

• 沸点：
  293.13°C (rough estimate)
• 密度：
  1.0851 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2932999099

制备方法与用途

类别：有毒物品

• 毒性分级：中毒
• 急性毒性：口服-大鼠 LD50: 500毫克/公斤
• 刺激数据：皮肤-兔子，10毫克/24小时，轻度刺激
• 可燃性危险特性：可燃；燃烧产生刺激烟雾
• 储运特性：库房应通风、低温干燥，并与食品原料分开存放
• 灭火剂：干粉、泡沫、砂土、二氧化碳及雾状水

反应信息

• 作为产物：
  描述：

  6-甲基-3-环己烯-1-羧酸 在 过氧乙酸 、 对甲苯磺酸 、 丙酮 、 苯 作用下， 生成 4-甲基-7-氧杂双环[4.1.0]庚烷-3-羧酸2-丙烯基酯
  参考文献：
  名称：

  Synthesis of Some Epoxy Vinyl Monomers by Epoxidation with Peracetic Acid¹

  摘要：

  DOI：

  10.1021/ja01522a048

文献信息

• METHODS FOR PRODUCING PHOTOSENSITIVE MICROPARTICLES
  申请人：Bowles Steven E.

  公开号：US20100221661A1

  公开（公告）日：2010-09-02

  Described are various methods of producing non-aqueous dispersions of photosensitive polymeric microparticles, comprising: (a) preparing one or more aqueous dispersions of a polymerizable component, at least one of which contains a photosensitive material and, wherein the polymerizable components comprise at least one hydrophilic functional group and/or at least one hydrophobic functional group; (b) subjecting the dispersion of (a) to conditions sufficient to form microparticles; (c) at least partially polymerizing the polymerizable component; (d) combining the dispersion with an organic continuous phase comprising an organic solvent; (e) removing water from the dispersion such that the final water content of the non-aqueous dispersion is less than 30 percent by weight; wherein e) is performed before or after d); and (f) reacting any acid functional groups on the surface of the microparticles with a reactive material having at least one epoxy functional group, at least one thiocarbonylthio functional group, at least one alkoxyamine functional group, or at least one halide functional group.

  本文描述了制备非水分散的光敏聚合微粒的各种方法，包括：(a)制备一种或多种聚合组分的水分散液，其中至少一种含有光敏材料，所述聚合组分包括至少一种亲水性功能基和/或至少一种疏水性功能基；(b)将(a)的分散液置于足以形成微粒的条件下；(c)至少部分聚合聚合组分；(d)将分散液与包含有机溶剂的有机连续相结合；(e)去除分散液中的水分，使得最终的非水分散液的水含量小于30重量％；其中e)在d)之前或之后执行；(f)用至少一种环氧功能基、至少一种硫代氨基酸功能基、至少一种烷氧胺功能基或至少一种卤素功能基的反应性材料反应微粒表面上的任何酸性功能基。
• FLUORINE- AND EPOXY GROUP-CONTAINING COPOLYMER, AND METHOD FOR PRODUCING SAME
  申请人：Showa Denko K.K.

  公开号：EP2578612B1

  公开（公告）日：2016-07-20
• FLUORINE AND EPOXY GROUP-CONTAINING COPOLYMER, AND METHOD FOR PRODUCING SAME
  申请人：Uchida Hiroshi

  公开号：US20130035461A1

  公开（公告）日：2013-02-07

  Provided is a fluorine- and epoxy group-containing copolymer with excellent workability at room temperature, high water-repellency, and excellent characteristics as a water vapor barrier. Also provided is an efficient method for producing said copolymer. The fluorine and epoxy group-containing copolymer is characterized by containing at least a monomer unit represented by general formula (1): Therein, R 1 -R 10 each independently represent an alkyl group having 1-3 carbon atoms or a hydrogen atom, R 11 is a hydrogen atom, methyl group, or phenyl group, and R 5 or R 6 can be linked with R 7 or R 8 to form a ring.} and a monomer unit represented by general formula (2): Therein, R 12 and R 13 each independently represent a hydrogen atom or a fluorine atom; R 14 represents a hydrogen atom, fluorine atom, methyl group or trifluoromethyl group, and R 15 represents a flourine atom or perfluoro group having at most 12 carbon atoms.}
• US8563213B2
  申请人：——

  公开号：US8563213B2

  公开（公告）日：2013-10-22
• US9034997B2
  申请人：——

  公开号：US9034997B2

  公开（公告）日：2015-05-19