N-(4-(dibenzo[b,d]furan-2-yl)phenyl)-9H-9,9-dimethyl-fluorene-2-amine | 1267248-51-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: N-(4-(dibenzo[b,d]furan-2-yl)phenyl)-9H-9,9-dimethyl-fluorene-2-amine
• 英文别名: N-(4-dibenzofuran-2-ylphenyl)-9,9-dimethylfluoren-2-amine
• CAS: 1267248-51-0
• 化学式: C₃₃H₂₅NO
• 分子量: 451.568
• InChiKey: KCRXTGANLWVIRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  35
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  25.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(4-(dibenzo[b,d]furan-2-yl)phenyl)-9H-9,9-dimethyl-fluorene-2-amine 、 2-bromospiro[fluorenyl-9,8'-indolo[3,2,1-de]acridine] 在 二(三叔丁基膦)钯 、 sodium t-butanolate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 3.0h， 以81%的产率得到N-(4-dibenzofuran-2-ylphenyl)-N-(9,9-dimethylfluoren-2-yl)spiro[1-azapentacyclo[10.7.1.02,7.08,20.014,19]icosa-2,4,6,8(20),9,11,14,16,18-nonaene-13,9'-fluorene]-2'-amine
  参考文献：
  名称：

  화합물 및 이를 포함하는 유기발광소자

  摘要：

  这份规格说明书提供了化合物和包含它的有机发光器件。

  公开号：

  KR20180027230A

文献信息

• AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT ELEMENTS USING SAME
  申请人：KATO Tomoki

  公开号：US20120146014A1

  公开（公告）日：2012-06-14

  Provided are an organic EL device material that reduce the driving voltage of an organic EL device and increase the lifetime of the device as compared with a conventional organic EL device material. Also provided are organic electroluminescence devices containing the organic EL device material.

  提供了一种有机EL器件材料，与传统有机EL器件材料相比，该材料降低了有机EL器件的驱动电压并增加了器件的使用寿命。同时，还提供了含有该有机EL器件材料的有机电致发光装置。
• Compounds and organic electronic devices
  申请人：Merck Patent GmbH

  公开号：US10355217B2

  公开（公告）日：2019-07-16

  The present invention relates to certain fluorenes, to the use of the compounds in an electronic device, and to an electronic device comprising at least one of these compounds. Furthermore, the present invention relates to a process for the preparation of the compounds and to a formulation and composition comprising one or more of the compounds.

  本发明涉及某些芴、这些化合物在电子设备中的用途以及包含至少一种这些化合物的电子设备。此外，本发明还涉及制备这些化合物的工艺，以及包含一种或多种这些化合物的配方和组合物。
• Aromatic amine derivatives and organic electroluminescent elements using same
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US11335858B2

  公开（公告）日：2022-05-17

  Provided are an organic EL device material capable of reducing the driving voltage of an organic EL device and increasing the lifetime of the device as compared with a conventional organic EL device material, specifically an aromatic amine derivative represented by N(Ara) (Arb) (Arc), and an organic EL device using the material. [Ara is represented by the formula (II). (In the formula (II): La represents a single bond or an arylene group; R1 to R4 each represent an alkyl group, an aryl group, or the like, and R3's or R4's, or R3 and R4 may be bonded to each other to form a ring; and o represents 0 to 3 and p represents 0 to 4.) Arb is represented by the formula (III). (in the formula (III), X represents NRa, O, or S, and Ra and R5 to R7 each represent an alkyl group, an aryl group, or the like, and R5's, R6's, or R7's adjacent to each other, or R5 and R6 may be bonded to each other to form a ring; n represents 2 to 4 when X represents NRa, and represents 0 to 4 when X represents O or S; and q represents 0 to 3, r and s each independently represent 0 to 4.) Arc represents an aryl group, or is represented by the formula (III).]

  本发明提供了一种有机电致发光器件材料，与传统的有机电致发光器件材料相比，该材料能够降低有机电致发光器件的驱动电压并延长该器件的使用寿命，特别是一种由 N(Ara) (Arb) (Arc) 表示的芳香胺衍生物，以及一种使用该材料的有机电致发光器件。[Ara 由式（II）表示。(在式(II)中La 代表单键或芳基；R1 至 R4 各自代表烷基、芳基或类似基团，R3 的或 R4 的或 R3 和 R4 可相互键合形成环；o 代表 0 至 3，p 代表 0 至 4）。Arb 由式（III）表示。(在式(III)中，X 代表 NRa、O 或 S，Ra 和 R5 至 R7 各自代表烷基、芳基或类似基团，且 R5、R6 或 R7 彼此相邻，或 R5 和 R6 可彼此键合形成环；当 X 代表 NRa 时，n 代表 2 至 4，当 X 代表 O 或 S 时，n 代表 0 至 4；且 q 代表 0 至 3，r 和 s 各自独立地代表 0 至 4)。Arc 代表芳基，或由式 (III) 表示]。
• VERBINDUNGEN UND ORGANISCHE ELEKTRONISCHE VORRICHTUNGEN
  申请人：Merck Patent GmbH

  公开号：EP3077477B1

  公开（公告）日：2018-02-28
• COMPOUNDS AND ORGANIC ELECTRONIC DEVICES
  申请人：MERCK PATENT GMBH

  公开号：US20160301005A1

  公开（公告）日：2016-10-13

  The present invention relates to certain fluorenes, to the use of the compounds in an electronic device, and to an electronic device comprising at least one of these compounds. Furthermore, the present invention relates to a process for the preparation of the compounds and to a formulation and composition comprising one or more of the compounds.