4,5,4',5'-Tetrakis-(3-chloro-propylsulfanyl)-[2,2']bi[[1,3]dithiolylidene] | 166671-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: 4,5,4',5'-Tetrakis-(3-chloro-propylsulfanyl)-[2,2']bi[[1,3]dithiolylidene]
• 英文别名: 2-[4,5-bis(3-chloropropylsulfanyl)-1,3-dithiol-2-ylidene]-4,5-bis(3-chloropropylsulfanyl)-1,3-dithiole
• CAS: 166671-12-1
• 化学式: C₁₈H₂₄Cl₄S₈
• 分子量: 638.729
• InChiKey: NPPRMCDQJCGSRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.77
• 重原子数：
  30.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  4,5,4',5'-Tetrakis-(3-chloro-propylsulfanyl)-[2,2']bi[[1,3]dithiolylidene] 在 mercury(II) diacetate 、 sodium iodide 、 亚磷酸三乙酯 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 氯仿 、 溶剂黄146 、 丙酮 、 甲苯 为溶剂， 反应 96.0h， 生成
  参考文献：
  名称：

  Syntheses, Unique Strained Molecular Structures, and Unusual Transannular Electronic Interactions of a Series of Crisscross-Overlapped Tetrathiafulvalenophanes

  摘要：

  A series of novel tetrathiafulvalenophanes has been synthesized, in which two tetrathiafulvalenes (TTF) are linked in a crisscross-overlapped arrangement by four alkylenedithio bridges. Their molecular structures were elucidated by X-ray crystal analyses, being characterized by the bent TTF skeletons as well as the unique stacking mode. The degree of the bend largely depends on both the length and conformational rigidity of the alkylenedithio chains. The short and rigid chains induce severe bending, which brings about a hypsochromical effect in the electronic absorption spectra. On the other hand, the long and flexible chains reduce the strain and make an inside cavity large enough to include a guest molecule. In addition, the less strained compounds can effect an intramolecular transannular Coulombic interaction between their two TTF units in solution, as demonstrated by multistage redox waves in the cyclic voltammograms. All the radical cation salts formed from these tetrathiafulvalenophanes have conductivities of the same order of 10(-6)-10(-7) S cm(-1), which are apparently independent of the donor and the counterion species.

  DOI：

  10.1021/jo962239x
• 作为产物：
  描述：

  4,5-Bis-(3-chloro-propylsulfanyl)-[1,3]dithiol-2-one 在 亚磷酸三乙酯 作用下， 以 苯 为溶剂， 反应 12.0h， 以78%的产率得到4,5,4',5'-Tetrakis-(3-chloro-propylsulfanyl)-[2,2']bi[[1,3]dithiolylidene]
  参考文献：
  名称：

  Crisscross-Overlapped Tetrathiafulvalenophanes

  摘要：

  DOI：

  10.1016/00404-0399(50)09194-

文献信息

• Oligomeric Tetrathiafulvalenes: Stable Caesium Tetrathiafulvalene- and 1,3-Dithiole-2-thionethiolates as Intermediates in the Synthesis of Pentakis(tetrathiafulvalenes)
  作者：Jesper Lau、Ole Simonsen、Jan Becher

  DOI：10.1055/s-1995-3941

  日期：1995.5

  Synthesis of stable caesium salts of tetrathiafulvalene- and 1,3-dithiole-2-thionethiolates and their reaction with tetrakis(iodoalkylthio)tetrathiafulvalene to produce pentakis(tetrathiafulvalenes) is presented. X-ray structure of the caesium salt of 1,3-dithiole-2-thione-5-methoxycarbonyl-4-thiolate reveals a highly conjugated system.

  介绍了四硫富戊烯和 1,3-二硫代-2-硫代硫醇的稳定铯盐的合成及其与四(碘烷基硫基)四硫富戊烯反应生成五(四硫富戊烯)的过程。1,3- 二硫代-2-硫酮-5-甲氧羰基-4-硫代酸铯盐的 X 射线结构显示了一个高度共轭的体系。