di-tert-butyl-4,4'-((4-(5-formylthiophen-2-yl)phenyl)azanediyl) dibenzoate | 1332724-74-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: di-tert-butyl-4,4'-((4-(5-formylthiophen-2-yl)phenyl)azanediyl) dibenzoate
• CAS: 1332724-74-9
• 化学式: C₃₃H₃₃NO₅S
• 分子量: 555.695
• InChiKey: HRSCHXOFKGAJTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.61
• 重原子数：
  40.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  72.91
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  di-tert-butyl-4,4'-((4-(5-formylthiophen-2-yl)phenyl)azanediyl) dibenzoate 在 三乙胺 、 三氟乙酸 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 14.0h， 生成 4,4'-(4-(5-(2,2-dicyanovinyl)thiophen-2-yl)phenylazanediyl)dibenzoic acid
  参考文献：
  名称：

  Arylamine-Based Dyes for p-Type Dye-Sensitized Solar Cells

  摘要：

  New arylamine-based sensitizers for p-type dye-sensitized solar cells (DSSCs) have been synthesized and used for p-type DSSCs. The best conversion efficiency reaches similar to 0.1%. Sensitizers with two anchoring carboxylic acids lead to higher open-circuit voltages, short-circuit currents, and energy conversion efficiencies.

  DOI：

  10.1021/ol202014x
• 作为产物：
  描述：

  N,N-di(4-benzoic acid tert-butyl ester)-4-(5’-(4,4,5,5-tetramethyl-[1,3,2]dioxoborolane-2-yl)-4,3’dihexyl-2,2’-bithien-5-yl)phenylamine 、 5-溴噻吩-2-甲醛 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 24.0h， 生成 di-tert-butyl-4,4'-((4-(5-formylthiophen-2-yl)phenyl)azanediyl) dibenzoate
  参考文献：
  名称：

  Arylamine-Based Dyes for p-Type Dye-Sensitized Solar Cells

  摘要：

  New arylamine-based sensitizers for p-type dye-sensitized solar cells (DSSCs) have been synthesized and used for p-type DSSCs. The best conversion efficiency reaches similar to 0.1%. Sensitizers with two anchoring carboxylic acids lead to higher open-circuit voltages, short-circuit currents, and energy conversion efficiencies.

  DOI：

  10.1021/ol202014x

文献信息

• Covalent Design for Dye-Sensitized H₂-Evolving Photocathodes Based on a Cobalt Diimine–Dioxime Catalyst
  作者：Nicolas Kaeffer、Julien Massin、Colette Lebrun、Olivier Renault、Murielle Chavarot-Kerlidou、Vincent Artero

  DOI：10.1021/jacs.6b05865

  日期：2016.9.28

  Dye-sensitized photoelectrochemical cells (DS-PECs) for water splitting hold promise for the large-scale storage of solar energy in the form of (solar) fuels, owing to the low cost and ease to process of their constitutive photoelectrode materials. The efficiency of such systems ultimately depends on our capacity to promote unidirectional light-driven electron transfer from the electrode substrate to a catalytic moiety. We report here on the first noble-metal free and covalent dye-catalyst assembly able to achieve photoelectrochemical visible light-driven H-2 evolution in mildly acidic aqueous conditions when grafted onto p-type NiO electrode substrate