6-Nitropurine | 95121-08-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• 英文名称: 6-Nitropurine
• 英文别名: 6-nitro-7H-purine
• CAS: 95121-08-7
• 化学式: C₅H₃N₅O₂
• 分子量: 165.111
• InChiKey: VKMDEROJLKHDOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  6-糠氨基嘌呤 在 dioperiodatoargenate(III) dihydrate 作用下， 生成 糠醇 、 6-Nitropurine
  参考文献：
  名称：

  Mechanistic investigation on the oxidation of kinetin by Ag(III) periodate complex in aqueous alkaline media: A kinetic approach

  摘要：

  The oxidation of amino acid, kinetin (KNT) by diperiodatoargentate(III) (DPA) in alkaline medium at a constant ionic strength of 0.5 mol dm−3 was studied spectrophtometrically. The reaction between KNT and DPA in alkaline medium exhibits 1: 3 stoichiometry (KNT: DPA). Intervention of free radicals was observed in the reaction. Based on the observed orders and experimental evidences, a mechanism involving the monoperiodatoargentate(III) (MPA) as the reactive oxidant species has been proposed. The products, furon-2-methanol and para-nitro-purine were identified by spot test and characterized by spectral studies. The rate constants and associated activation parameters for the proposed mechanism as well as the thermodynamic quantities for different equilibrium steps are reported and discussed.

  DOI：

  10.1007/s12039-010-0077-9