1-N-[4-(4-methoxy-N-(4-methoxyphenyl)anilino)phenyl]-4-N,4-N-bis(4-methoxyphenyl)-1-N-[4-([1,3]oxazolo[5,4-f][1,10]phenanthrolin-2-yl)phenyl]benzene-1,4-diamine | 1260425-56-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-N-[4-(4-methoxy-N-(4-methoxyphenyl)anilino)phenyl]-4-N,4-N-bis(4-methoxyphenyl)-1-N-[4-([1,3]oxazolo[5,4-f][1,10]phenanthrolin-2-yl)phenyl]benzene-1,4-diamine
• CAS: 1260425-56-6
• 化学式: C₅₉H₄₆N₆O₅
• 分子量: 919.051
• InChiKey: XGPXFBXLJPMHHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.6
• 重原子数：
  70
• 可旋转键数：
  14
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  98.4
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 N,N-bis[4-(di-4-methoxyphenylamino)phenyl]-N-(p-benzaldehyde)amine 在 ammonium acetate 、 溶剂黄146 作用下， 以15%的产率得到1-N-[4-(4-methoxy-N-(4-methoxyphenyl)anilino)phenyl]-4-N,4-N-bis(4-methoxyphenyl)-1-N-[4-([1,3]oxazolo[5,4-f][1,10]phenanthrolin-2-yl)phenyl]benzene-1,4-diamine
  参考文献：
  名称：

  Accumulative Charge Separation Inspired by Photosynthesis

  摘要：

  Molecular systems that follow the functional principles of photosynthesis have attracted increasing attention as a method for the direct production of solar fuels. This could give a major carbon-neutral energy contribution to our future society. An outstanding challenge in this research is to couple the light-induced charge separation (which generates a single electron-hole pair) to the multielectron processes of water oxidation and fuel generation. New design considerations are needed to allow for several cycles of photon absorption and charge separation of a single artificial photosystem. Here we demonstrate a molecular system with a regenerative photosensitizer that shows two successive events of light-induced charge separation, leading to high-yield accumulation of redox equivalents on single components without sacrificial agents.

  DOI：

  10.1021/ja104809x