Fe(6-difluoro-N-(1-(6-(1-methyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)benzenamine)2FeCl4 | 1092500-97-4

• 英文名称: Fe(6-difluoro-N-(1-(6-(1-methyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)benzenamine)2FeCl4
• CAS: 1092500-97-4
• 化学式: C₄₂H₃₂F₄FeN₈*Cl₄Fe
• 分子量: 978.269
• InChiKey: OWOBEYSMSVUIDT-XBGHSUNWSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  iron(II) chloride tetrahydrate 、 6-difluoro-N-(1-(6-(1-methyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)benzenamine 以 乙醇 为溶剂， 以79.5%的产率得到Fe(6-difluoro-N-(1-(6-(1-methyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)benzenamine)2FeCl4
  参考文献：
  名称：

  Tridentate NˆNˆN iron(II) and cobalt(II) complexes of ion-paired structures: Synthesis, characterization and magnetism

  摘要：

  Two kinds of ion-paired iron and cobalt complexes ligated by 2-(benzimidazolyl)-6-(1-(arylimino)ethyl)pyridyl [iron (1a) and cobalt (1b)] or N-(pyridin-2-yl)methylene)-quinolin-8-amine (iron, 2a) were synthesized and well characterized by IR, EA and X-ray diffraction analysis. They were confirmed to be in the form of [ML2](2+)[MCl4](2-) or [ML2](2+)2[MCl4](1-) and the cations took octahedral coordinated geometry. Structure research indicated that complex 1a was in low-spin state while complex 1b was in high-spin state. Furthermore, their magnetic susceptibility measurements were performed and the complexes showed interesting magnetic properties. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.03.027