bis(3-amino-1-nitroguanidine)dinitratocopper(II) | 1492058-93-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(3-amino-1-nitroguanidine)dinitratocopper(II)
• 英文别名: Co(ANG)2(NO3)2；copper;1-amino-2-nitroguanidine;dinitrate
• CAS: 1492058-93-1
• 化学式: C₂H₁₀CuN₁₂O₁₀
• 分子量: 425.722
• InChiKey: HXDYJPUVOROEJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.57
• 重原子数：
  25
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  370
• 氢给体数：
  6
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  1-氨基-3-硝基胍 、 copper(II) nitrate trihydrate 以 水 为溶剂， 以15%的产率得到bis(3-amino-1-nitroguanidine)dinitratocopper(II)
  参考文献：
  名称：

  Transition Metal Complexes of 3-Amino-1-nitroguanidine as Laser Ignitible Primary Explosives: Structures and Properties

  摘要：

  3-Amino-1-nitroguanidine (ANQ, 2) was synthesized via hydrazinolysis of nitroguanidine. By dissolving 2 in solutions containing transition metal salts, several complexes M2+(ANQ)(2)X-2(H2O)(y) with M2+ = Co, Ni, Cu, Zn as well as M(ANQ)(2)X(H2O)(y) with M = Ag could be isolated. In these cases, nitrate as well as perchlorate and chloride served as the respective anions X. Additionally, the ANQ complexes of Co, Ni, and Ag with dinitramide as the anion were synthesized from ANQ and silver dinitramide and by reacting the cobalt and nickel ANQ perchlorate complexes with ammonium dinitramide. The crystal structures of all described complexes were determined by low temperature single-crystal X-ray diffraction. Additionally, they were characterized using IR spectroscopy and elemental analysis. The decomposition temperatures were determined by differential scanning calorimetry and the sensitivities toward impact and friction were assessed using a BAM drophammer and a BAM friction tester (BAM = Bundesanstalt fur Materialforschung und -prufung). Additionally, the sensitivity toward electrostatic discharge was determined on a small-scale ESD device. The potential use of the nitrate, dinitramide and perchlorate containing species as primary explosives was investigated in a laser ignition test.

  DOI：

  10.1021/ic402038x