bis(dimethylaminophenyl) telluridiiodide | 63999-19-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(dimethylaminophenyl) telluridiiodide
• 英文别名: bis-(4-dimethylamino-phenyl)-diiodo-λ⁴-tellane；Bis-(4-dimethylamino-phenyl)-dijod-λ⁴-tellan；4.4'-Bis-dimethylamino-diphenyltellurdijodid；4-[[4-(dimethylamino)phenyl]-diiodo-lambda4-tellanyl]-N,N-dimethylaniline；4-[[4-(dimethylamino)phenyl]-diiodo-λ4-tellanyl]-N,N-dimethylaniline
• CAS: 63999-19-9
• 化学式: C₁₆H₂₀I₂N₂Te
• 分子量: 621.757
• InChiKey: MEXXNZUUERTQHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.25
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tin(II) iodide 、 bis(dimethylaminophenyl) telluridiiodide 以 乙醇 为溶剂， 以43%的产率得到bis(N,N-dimethylanilinium) ditellurium(IV) decaiodide
  参考文献：
  名称：

  [C₆H₅NH(CH₃)₂]₂Te₂I₁₀:  Secondary I···I Bonds Build up a 3D Network

  摘要：

  The crystal structure of [C6H5NH(CH3)(2)](2)Te2I10 consists of the N,N-dimethylanilinium cation and a hitherto unreported tellurium iodide anion Te2I102- [crystal data: C(8)H(12)NTel(5), monoclinic, P2(1)/c, a = 9.4787(2) Angstrom, b = 14.2874(3) Angstrom, c = 13.6869(3) Angstrom, beta = 95.1918(8)degrees, V = 1845.96(7) Angstrom(3), Z = 4]. The Te2I102- dianion is based on two edge-sharing Tel(6)(2-) octahedra, and interestingly, it builds up a three-dimensional Te(IV)-I open framework through extensive interconnecting (II)-I-... contacts. These (II)-I-... contacts (3.66-3.80 Angstrom) are significantly shorter than the corresponding sum of van der Waals radii (4.0 Angstrom) and may potentially promote charge carrier migration throughout the Te-I network. This material can also be drop-cast into thin films from a heated DMF solution.

  DOI：

  10.1021/ic049443k
• 作为产物：
  描述：

  bis(4-dimethylaminophenyl)telluride 在 硫酰碘 作用下， 以 四氯化碳 为溶剂， 生成 bis(dimethylaminophenyl) telluridiiodide
  参考文献：
  名称：

  Sadekov,I.D. et al., Journal of general chemistry of the USSR, 1977, vol. 47, p. 1202 - 1209

  摘要：

  DOI：

文献信息

• Morgan; Burgess, Journal of the Chemical Society, 1929, p. 1105
  作者：Morgan、Burgess

  DOI：——

  日期：——
• Sadekov,I.D. et al., Journal of general chemistry of the USSR, 1977, vol. 47, p. 1202 - 1209
  作者：Sadekov,I.D. et al.

  DOI：——

  日期：——
• [C₆H₅NH(CH₃)₂]₂Te₂I₁₀:  Secondary I···I Bonds Build up a 3D Network
  作者：Jacqueline M. Ryan、Zhengtao Xu

  DOI：10.1021/ic049443k

  日期：2004.7.1

  The crystal structure of [C6H5NH(CH3)(2)](2)Te2I10 consists of the N,N-dimethylanilinium cation and a hitherto unreported tellurium iodide anion Te2I102- [crystal data: C(8)H(12)NTel(5), monoclinic, P2(1)/c, a = 9.4787(2) Angstrom, b = 14.2874(3) Angstrom, c = 13.6869(3) Angstrom, beta = 95.1918(8)degrees, V = 1845.96(7) Angstrom(3), Z = 4]. The Te2I102- dianion is based on two edge-sharing Tel(6)(2-) octahedra, and interestingly, it builds up a three-dimensional Te(IV)-I open framework through extensive interconnecting (II)-I-... contacts. These (II)-I-... contacts (3.66-3.80 Angstrom) are significantly shorter than the corresponding sum of van der Waals radii (4.0 Angstrom) and may potentially promote charge carrier migration throughout the Te-I network. This material can also be drop-cast into thin films from a heated DMF solution.