cis-tetrachlorobis(propiononitrile)tin(IV) propiononitrile solvate | 634612-30-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: cis-tetrachlorobis(propiononitrile)tin(IV) propiononitrile solvate
• 英文别名: propanenitrile;tin(4+);tetrachloride
• CAS: 634612-30-9
• 化学式: C₃H₅N*C₆H₁₀Cl₄N₂Sn
• 分子量: 425.76
• InChiKey: NAYSZRFGYJFNGV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -9.6
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  71.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  四氯化锡 、 丙腈 以 further solvent(s) 为溶剂， 生成 cis-tetrachlorobis(propiononitrile)tin(IV) propiononitrile solvate
  参考文献：
  名称：

  cis-Bis(acetonitrile)tetrachlorotin(IV) acetonitrile solvate,cis-tetrachlorobis(propiononitrile)tin(IV) propiononitrile solvate,cis-tetrachlorobis(isobutyronitrile)tin(IV),cis-tetrachlorobis(cyclohexanecarbonitrile)tin(IV) andcis-tetrachlorobis(o-toluonitrile)tin(IV), all determined atca150 K

  摘要：

  The structures of the title compounds, [SnCl4(C2H3N)(2)] .C2H3N, [SnCl4(C3H5N)(2)] . C3H5N, [SnCl4(C4H7N)(2)], [SnCl4( C7H11N)(2)] and [SnCl4(C8H7N)(2)], were determined with the intention of examining the effect of various substituent types in nitrile ligands, RCN, behaving in a common sigma-donor situation {in this case, as cis-bis complexes with SnCl4, viz. [SnCl4(RCN)(2)]}, on (i) the strength of complex formation with the metal atom and (ii) other bonding behaviour of the metal ( for example, trans effects). The five structures exhibit no non-trivial systematic perturbation that can be said to be contingent on the substituent type.

  DOI：

  10.1107/s0108270103012642