| 1372529-12-8

• CAS: 1372529-12-8
• 化学式: C₇₂H₈₂ClN₂OPt*F₆Sb
• 分子量: 1457.73
• InChiKey: ZNLIPOGQWDZTLA-DCJDEVRFSA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 KOH 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Monomeric Platinum(II) Hydroxides Supported by Sterically Dominant α-Diimine Ligands

  摘要：

  The use of two new highly sterically bulky a-diimine ligands for the stabilization of neutral, monomeric platinum(H) hydroxo complexes is described. Halide abstraction from LPtCl2 complexes of these ligands in the presence of water, followed by deprotonation of the cationic aquo complex, leads to LPt(OH)Cl and LPt(OH)(2). The latter can be reprotonated with HNTf2 to yield a highly fluxional hydroxoaquoplatinum(II) cation.

  DOI：

  10.1021/ic300337a
• 作为产物：
  描述：

  silver hexafluoroantimonate 、 、 水 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Monomeric Platinum(II) Hydroxides Supported by Sterically Dominant α-Diimine Ligands

  摘要：

  The use of two new highly sterically bulky a-diimine ligands for the stabilization of neutral, monomeric platinum(H) hydroxo complexes is described. Halide abstraction from LPtCl2 complexes of these ligands in the presence of water, followed by deprotonation of the cationic aquo complex, leads to LPt(OH)Cl and LPt(OH)(2). The latter can be reprotonated with HNTf2 to yield a highly fluxional hydroxoaquoplatinum(II) cation.

  DOI：

  10.1021/ic300337a