copper;azane;platinum(2+);tetracyanide | 329907-08-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: copper;azane;platinum(2+);tetracyanide
• CAS: 329907-08-6
• 化学式: C₄H₁₂CuN₈Pt
• 分子量: 430.819
• InChiKey: NVCCECSYRXEEPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.03
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  99.2
• 氢给体数：
  4
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 barium tetracyanoplatinate(II) tetrahydrate 在 NH₄OH 作用下， 以 水 为溶剂， 生成 copper;azane;platinum(2+);tetracyanide
  参考文献：
  名称：

  An Extremly Bent Cyanide Bridge in Crystals of [(CN)₃Pt(μ-CN)Cu(NH₃)₄]. Influence of Electrostatic Forces on the Nature and Geometry of Bridging Cyanides in the Solid State

  摘要：

  The dinuclear heterometallic complex [(CN)(3)Pt(mu -CN)Cu(NH3)(4)] has been obtained in the solid state, and its structure has been determined by X-ray diffraction techniques at two temperatures (102 and 233 It). C4H12CuN8- Pt crystallizes in the orthorhombic system, with a = 14.554(3) Angstrom, b = 7.1901(12) Angstrom, c = 10.369(2) Angstrom, and V = 1085.1(3) Angstrom (3) at 102 K (a = 14.5091(10) Angstrom, b = 7.2739( F) Angstrom, c = 10.4570(7) Angstrom, and V = 1103.61(12) Angstrom (3) at 233 K), in space group Pnma, with Z = 4. The Pt and Cu atoms are linked by a CN bridge that presents a very bent C=N-Cu angle (120.1(6)degrees at 102 K). The C=N and N-Cu distances at 102 K are 1.147(10) and 2.394(7) A, respectively. [(CN)(3)Pt(mu -CN)Cu(NH3)(4)] is embedded in an extensive electrostatic net formed by (N)H...N(C) interactions which, it is concluded, play an important role in the extreme deviation from linearity observed for the C=N-Cu angle.

  DOI：

  10.1021/ic000734c