N-(4-oxopent-2-ylidene)-N',N'-dimethylethylenediamine | 104488-95-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-oxopent-2-ylidene)-N',N'-dimethylethylenediamine
• 英文别名: 4-(dimethylaminoethyl-imino)-2-pentanone；4-[2-(dimethylamino)ethylimino]pentan-2-one
• CAS: 104488-95-1
• 化学式: C₉H₁₈N₂O
• 分子量: 170.255
• InChiKey: YPHLYXXEXBWEFV-UHFFFAOYSA-N

物化性质

• 沸点：
  69 °C(Press: 0.40 Torr)
• 密度：
  0.91±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  32.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N,N-二甲基乙二胺 、 乙酰丙酮 在 硝基甲烷 作用下， 以 苯 为溶剂， 反应 72.0h， 以98%的产率得到N-(4-oxopent-2-ylidene)-N',N'-dimethylethylenediamine
  参考文献：
  名称：

  Facile synthesis of allylic nitro compounds by N,N-dimethylethylenediamine-catalyzed condensation of aliphatic and alicyclic ketones with primary nitroalkanes

  摘要：

  DOI：

  10.1021/jo00373a007

文献信息

• Metal Complexes of Polydentate Beta-Ketoiminates
  申请人：Lei Xinjian

  公开号：US20070248754A1

  公开（公告）日：2007-10-25

  A plurality of metal-containing complexes of a polydentate beta-ketoiminate, one embodiment of which is represented by the structure are shown: wherein M is a metal such as calcium, strontium, barium, scandium, yttrium, lanthanum, titanium, zirconium, vanadium, tungsten, manganese, cobalt, iron, nickel, ruthenium, zinc, copper, palladium, platinum, iridium, rhenium, osmium; wherein R 1 is selected from the group consisting of alkyl, fluoroalkyl, cycloaliphatic, and aryl, having from 1 to 10 carbon atoms; R 2 can be from the group consisting of hydrogen, alkyl, alkoxy, cycloaliphatic, and aryl; R 3 is linear or branched selected from the group consisting of alkylene, fluoroalkyl, cycloaliphatic, and aryl; R 4 is an alkylene bridge; R 5-6 are individually linear or branched selected from the group consisting of alkyl, fluoroalkyl, cycloaliphatic, aryl, and they can be connected to form a ring containing carbon, oxygen, or nitrogen atoms; n is an integer equal to the valence of the metal M.

  一种多个含金属的多牙酮亚胺配合物，其中一种实施例的结构如下：其中M是金属，例如钙、锶、钡、钪、钇、镧、钛、锆、钒、钨、锰、钴、铁、镍、钌、锌、铜、钯、铂、铱、铼、锇；其中R1选择自烷基、氟烷基、环烷基和芳基等含1至10个碳原子的基团；R2可以是氢、烷基、烷氧基、环烷基和芳基等基团；R3是线性或支链的烷基、氟烷基、环烷基和芳基等基团；R4是烷基桥；R5-6分别是线性或支链的烷基、氟烷基、环烷基、芳基，它们可以连接形成含碳、氧或氮原子的环；n是等于金属M的价的整数。
• Metal complexes of polydentate beta-ketoiminates
  申请人：Air Products and Chemicals, Inc.

  公开号：US07947814B2

  公开（公告）日：2011-05-24

  A plurality of metal-containing complexes of a polydentate beta-ketoiminate, one embodiment of which is represented by the structure are shown: wherein M is a metal such as calcium, strontium, barium, scandium, yttrium, lanthanum, titanium, zirconium, vanadium, tungsten, manganese, cobalt, iron, nickel, ruthenium, zinc, copper, palladium, platinum, iridium, rhenium, osmium; wherein R1 is selected from the group consisting of alkyl, fluoroalkyl, cycloaliphatic, and aryl, having from 1 to 10 carbon atoms; R2 can be from the group consisting of hydrogen, alkyl, alkoxy, cycloaliphatic, and aryl; R3 is linear or branched selected from the group consisting of alkylene, fluoroalkyl, cycloaliphatic, and aryl; R4 is an alkylene bridge; R5-6 are individually linear or branched selected from the group consisting of alkyl, fluoroalkyl, cycloaliphatic, aryl, and they can be connected to form a ring containing carbon, oxygen, or nitrogen atoms; n is an integer equal to the valence of the metal M.

  一种聚齿β-酮亚胺金属含配合物的多元体系，其中一种实施例由以下结构表示：其中M是金属，例如钙、锶、钡、钪、钇、镧、钛、锆、钒、钨、锰、钴、铁、镍、钌、锌、铜、钯、铂、铱、铼、锇；其中R1选自由1至10个碳原子的烷基、氟烷基、环烷基和芳基的群组；R2可以来自氢、烷基、烷氧基、环烷基和芳基的群组；R3是线性或支链的，选自烷基、氟烷基、环烷基和芳基的群组；R4是烷基桥；R5-6分别选自由碳、氧或氮原子组成的环中的烷基、氟烷基、环烷基和芳基的群组，它们可以连接形成环；n是等于金属M的价数的整数。