2-(sec-butyl)-1,3-dioxepane | 875819-58-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: 2-(sec-butyl)-1,3-dioxepane
• CAS: 875819-58-2
• 化学式: C₉H₁₈O₂
• 分子量: 158.241
• InChiKey: BJACQMAHQMPYEZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.19
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1,4-丁二醇 、 丁酮 在 sulfonic group functionalized polyacrylonitrile preoxidated nanofiber mat 作用下， 以 环己烷 为溶剂， 反应 4.0h， 以88.76%的产率得到2-(sec-butyl)-1,3-dioxepane
  参考文献：
  名称：

  Sulfonic groups functionalized preoxidated polyacrylonitrile nanofibers and its catalytic applications

  摘要：

  A SO3H-bearing nanofiber mat was synthesized and investigated as a novel heterogeneous acid catalyst. Preoxidated polyacrylonitrile nanofiber mat was prepared via electrospinning and heat treatment, and then reacted with chlorosulfuric acid to introduce the sulfonic groups. The nanofiber mat owned high acidity of 2.99 mmol/g. The preoxidation and sulfonation were examined by FT-IR spectroscopy. elemental analysis and X-ray diffraction spectroscopy (XRD). The fiber morphologies were characterized by scanning electron microscopy (SEM). The catalytic activities and reuse of the prepared nanofiber mat solid acid catalyst have been evaluated for the acetalization and esterification. The regular fiber mat structure could significantly facilitate the recovery and reuse of the catalyst. The excellent catalytic performance and easy recycling made the novel fiber mat solid acid hold great potential for the green chemical processes. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2012.07.034