N,N'-(pyridine-2,6-diyl)bis(3-(4-((3,4,5-tris(dodecyloxy)benzyl)oxy)phenyl)propanamide) compound with 7,8,10-trimethylbenzo[g]pteridine-2,4(3H,10H)-dione (1:1) | 1452453-29-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 蝶啶及其衍生物
• 英文名称: N,N'-(pyridine-2,6-diyl)bis(3-(4-((3,4,5-tris(dodecyloxy)benzyl)oxy)phenyl)propanamide) compound with 7,8,10-trimethylbenzo[g]pteridine-2,4(3H,10H)-dione (1:1)
• CAS: 1452453-29-0
• 化学式: C₁₃H₁₂N₄O₂*C₁₀₉H₁₇₉N₃O₁₀
• 分子量: 1947.9
• InChiKey: OUMCDSXQGCYIPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  33.92
• 重原子数：
  141.0
• 可旋转键数：
  86.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  225.57
• 氢给体数：
  3.0
• 氢受体数：
  16.0

反应信息

• 作为产物：
  描述：

  2,6-bis{3-[4-(3,4,5-tridodecyloxybenzyloxy)phenyl]propanoylamino}pyridine 、 光黃素 以 氘代氯仿 为溶剂， 生成 N,N'-(pyridine-2,6-diyl)bis(3-(4-((3,4,5-tris(dodecyloxy)benzyl)oxy)phenyl)propanamide) compound with 7,8,10-trimethylbenzo[g]pteridine-2,4(3H,10H)-dione (1:1)
  参考文献：
  名称：

  Non-covalently dendronized flavins as organocatalysts for aerobic reduction of olefins

  摘要：

  A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.082